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Framed aromatic polyurethanes based on an anionic macroinitiator, 4,4'-diphenylmethane diisocyanate, and 4,4'-dihydroxy-2,2-diphenylpropane: Metal-complex modification

  • Modification of Polymers
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Abstract

Metal complexes are prepared from poly(oxyethylene glycol) and iron(III) chloride and studied as modifiers of framed aromatic polyurethanes. The latter polymers are synthesized on the basis of macroinitiators, 4,4'-dihydroxy-2,2-diphenylpropane, and polyisocyanate, which is a mixture of 4,4'-diphenylmethane diisocyanate and its branched derivatives. The interaction of iron(III) chloride with poly(oxyethylene glycol) is accompanied by redox processes that lead to its degradation and partial reduction of Fe(III) to Fe(II). Aromatic polyurethanes are modified in the concentration range of metal complexes from 0.5 to 20%. At a concentration of metal complexes of 4–7%, the polymer shows high mechanical characteristics and excellent thermal stability. The framed structure of aromatic polyurethanes hampers the effective contacts of coordinately bonded Fe atoms that are present in various oxidation states.

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Authors and Affiliations

  1. Кazan National Research Technological University, ul. Karla Marksa 68, Кazan, 420015, Russia

    I. M. Davletbaeva, I. I. Zaripov, R. R. Karimullin & A. M. Gumerov

  2. Кazan (Volga Region) Federal University, Kremlevskaya ul. 18, Кazan, 420008, Russia

    I. M. Davletbaeva

  3. Кazan National Research Technical University, ul. Karla Marksa 10, Kazan, 420111, Russia

    R. S. Davletbaev

  4. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, str. 24, Krasnoyarsk, 660036, Russia

    G. V. Burmakina

  5. Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk, 660041, Russia

    G. V. Burmakina

Authors
  1. I. M. Davletbaeva
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  2. I. I. Zaripov
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  3. R. R. Karimullin
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  4. A. M. Gumerov
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  5. R. S. Davletbaev
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  6. G. V. Burmakina
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Corresponding author

Correspondence to I. M. Davletbaeva.

Additional information

Original Russian Text © I.M. Davletbaeva, I.I. Zaripov, R.R. Karimullin, A.M. Gumerov, R.S. Davletbaev, G.V. Burmakina, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2017, Vol. 59, No. 1, pp. 57–67.

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Davletbaeva, I.M., Zaripov, I.I., Karimullin, R.R. et al. Framed aromatic polyurethanes based on an anionic macroinitiator, 4,4'-diphenylmethane diisocyanate, and 4,4'-dihydroxy-2,2-diphenylpropane: Metal-complex modification. Polym. Sci. Ser. B 59, 69–79 (2017). https://doi.org/10.1134/S1560090417010055

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  • DOI: https://doi.org/10.1134/S1560090417010055

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