Abstract
4-(2-Hydroxyphenyl)-1,3,5-triazin-2-ylcyanamides reacted with sodium azide to give N-(tetrazol-5-yl)-1,3,5-triazin-2-amines, and their reaction with allyl bromide afforded allyl(1,3,5-triazin-2-yl)cyanamides. Acetylation of 4-(2-hydroxyphenyl)-1,3,5-triazin-2-amines involved only the amino group with formation of diacetylamino derivatives, whereas the phenolic hydroxy group remained intact. The reaction of triazinamines with 2,5-dimethoxytetrahydrofuran in the presence of P2O5 gave pyrrolyl-substituted triazines.
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Original Russian Text © E.Yu. Shasheva, N.I. Vikrishchuk, L.D. Popov, S.A. Borodkin, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 10, pp. 1544–1548.
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Shasheva, E.Y., Vikrishchuk, N.I., Popov, L.D. et al. New functionalized amino derivatives of 2-hydroxyphenyl-1,3,5-triazines. Russ J Org Chem 53, 1573–1577 (2017). https://doi.org/10.1134/S107042801710013X
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DOI: https://doi.org/10.1134/S107042801710013X