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Synthesis and spectral properties of lutetium complexes with unsymmetrical phthalocyanines and sandwich complexes based thereon containing tetraanthraquinonoporphyrazine fragments

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Abstract

Joint condensation of 4,5-bis(4-hexadecyloxyphenoxy)phthalonitrile (A) and tetrachlorophthalonitrile (B) in boiling hexan-1-ol in the presence of lithium hexan-1-olate and subsequent reaction with LuCl3 · 6 H2O gave single-decker lutetium complexes with unsymmetrical phthalocyanines (AABB, ABAB). Reactions of the latter with 9,10-dioxo-9.10-dihydroanthraquinone-2,3-dicarbonitrile afforded mixed-ligand double-decker lutetium complexes containing tetraanthraquinonoporphyrazine as one of the ligands. Spectral properties of the synthesized complexes were studied, and all complexes were found to exhibit red fluorescence.

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Authors and Affiliations

  1. Research Institute of Macroheterocyclic Compounds, Ivanovo State University of Chemistry, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    A. V. Borisov, M. V. Korel’chuk, E. S. Ageeva, N. E. Galanin & G. P. Shaposhnikov

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  1. A. V. Borisov
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  2. M. V. Korel’chuk
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  3. E. S. Ageeva
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  4. N. E. Galanin
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  5. G. P. Shaposhnikov
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Correspondence to A. V. Borisov.

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Original Russian Text © A.V. Borisov, M.V. Korel’chuk, E.S. Ageeva, N.E. Galanin, G.P. Shaposhnikov, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 7, pp. 1004–1010.

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Borisov, A.V., Korel’chuk, M.V., Ageeva, E.S. et al. Synthesis and spectral properties of lutetium complexes with unsymmetrical phthalocyanines and sandwich complexes based thereon containing tetraanthraquinonoporphyrazine fragments. Russ J Org Chem 50, 986–992 (2014). https://doi.org/10.1134/S1070428014070094

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  • DOI: https://doi.org/10.1134/S1070428014070094

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