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Optical resolution of racemic 4-hydroxy-3,5-diisobornylbenzaldehyde

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Abstract

Optical resolution of racemic 4-hydroxy-3,5-diisobornylbenzaldehyde was accomplished via transformation into diastereoisomeric esters by treatment with (1S)-camphanoyl chloride. The absolute configuration of the enantiomers was determined on the basis of the X-ray diffraction data for one diastereoisomeric camphanate.

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Authors and Affiliations

  1. Institute of Chemistry, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, 167982, Russia

    E. V. Buravlev, I. Yu. Chukicheva & A. V. Kutchin

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    K. Yu. Suponitskii

Authors
  1. E. V. Buravlev
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  2. I. Yu. Chukicheva
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  3. K. Yu. Suponitskii
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  4. A. V. Kutchin
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Correspondence to E. V. Buravlev.

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Dedicated to Full Member of the Russian Academy of Sciences G.A. Tolstikov on his 80th anniversary

Original Russian Text © E.V. Buravlev, I.Yu. Chukicheva, K.Yu. Suponitskii, A.V. Kutchin, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 1, pp. 69–75.

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Buravlev, E.V., Chukicheva, I.Y., Suponitskii, K.Y. et al. Optical resolution of racemic 4-hydroxy-3,5-diisobornylbenzaldehyde. Russ J Org Chem 49, 60–66 (2013). https://doi.org/10.1134/S1070428013010119

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  • DOI: https://doi.org/10.1134/S1070428013010119

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