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Synthesis of catalyst based on sol microspheres coated with pyrolytic tungsten and study of its influence on production of metallic germanium

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Abstract

Pyrolytic tungsten coatings were deposited onto the surface of sol microspheres with tungsten hexacarbonyl used as precursor. A method was developed for reduction of germanium tetrachloride in the presence of a catalyst based on sol microspheres coated with pyrolytic tungsten. The method makes it possible to reduce the process temperature and diminish the number of stages in production of germanium. The kinetic characteristics of the catalytic reduction of germanium tetrachloride with hydrogen were determined.

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Authors and Affiliations

  1. Nizhny Novgorod State Medical Academy, Ministry of Health of the Russian Federation, pl. Minina & Pozharskogo 10/1, Nizhny Novgorod, 603005, Russia

    A. V. Kadomtseva

  2. Nizhny Novgorod State Technical University n.a. R.E. Alekseev, ul. Minina 24, Nizhny Novgorod, 603155, Russia

    A. V. Kadomtseva

  3. Razuvaev Institute of Organometallic Chemistry, ul. Tropinina 49, Nizhny Novgorod, 603137, Russia

    A. M. Ob”edkov, M. N. Semenov & B. S. Kaverin

  4. Institute for Physics of Microstructures, Russian Academy of Sciences, der. Afonino, Nizhny Novgorod, 603087, Russia

    S. A. Gusev

Authors
  1. A. V. Kadomtseva
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  2. A. M. Ob”edkov
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  3. M. N. Semenov
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  4. B. S. Kaverin
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  5. S. A. Gusev
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Corresponding author

Correspondence to A. V. Kadomtseva.

Additional information

Original Russian Text © A.V. Kadomtseva, A.M. Ob”edkov, M. N. Semenov, B.S. Kaverin, S.A. Gusev, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 11, pp. 1428−1437.

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Kadomtseva, A.V., Ob”edkov, A.M., Semenov, M.N. et al. Synthesis of catalyst based on sol microspheres coated with pyrolytic tungsten and study of its influence on production of metallic germanium. Russ J Appl Chem 89, 1797–1805 (2016). https://doi.org/10.1134/S1070427216110100

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  • DOI: https://doi.org/10.1134/S1070427216110100

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