Abstract
Systems based on refractory ZrB2 and HfB2 powders are the most promising for fabrication of newgeneration aircraft parts working under extreme conditions. The complexity of sintering of these powders is overcome by using the spark plasma sintering method (SPS/FAST) with additional inductive heating. The sintering of HfB2-SiC samples separately in the SPS mode or by inductive heating at 100 deg min−1 failed to provide samples with required quality. It was shown that the relative density differential for samples 100 mm in diameter, sintered in the combined-heating mode [simultaneously by inductive and spark plasma sintering (SPS)] does not exceed 2.4%. Oxidation resistance tests of the samples at temperatures T ≥ 1800°C demonstrated that further studies of the HfB2-SiC system as a material for aircraft articles are needed.
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References
Matovic, B. and Yano, T., Handbook of Advanced Ceramics, Shigeyuki Somiya, Ed., Oxford, 2013, chapter 3.1, pp. 225–244.
Opeka, M.M., Talmy, I.G., and Zaykoski, J.A., J. Mater. Sci., 2004, vol. 39, pp. 5887–5904.
Grashchenkov, D.V. and Chursova, L.V., Aviats. Mater. Tekhnol., 2012, no. S, pp. 231–242.
Chainikova, A.S., Orlova, L.A., Popovich, N.V., et al., Aviats. Mater. Tekhnol., 2014, no. 3, pp. 45–54.
Kablov, E.N., Ospennikova, O.G., and Vershkov, A.V., Trudy VIAM, 2013, no. 2, paper 01 (viam-works.ru).
Simonenko, E.P., Simonenko, N.P., Sevast’yanov, V.G., et al., Kompoz. Nanostrukt., 2011, no. 4, pp. 52–64.
Kablov, E.N., Grashchenkov, D.V., Isaeva, N.V., et al., Steklo Keram., 2012, no. 4, pp. 7–11.
Kablov, E.N., Grashchenkov, D.V., Isaeva, N.V., and Solntsev, S.S., Ross. Khim. Zh., 2010, vol. 54, no. 1, pp. 20–24.
Ghosh, D. and Subhashy, G., Handbook of Advanced Ceramics, Elsevier Inc., 2013, 2nd ed., chapter 3.1, pp. 267–299.
Fahrenholtz, W. and Hilmas, G., J. Am. Ceram. Soc., 2007, vol. 90, no. 5, pp. 1347–1363.
Voitovich, R.F. and Pugach, E.A., Okislenie tugoplavkikh soedinenii: Spravochnik (Oxidation of Refractory Compounds: Reference Book, Kiev: Naukova Dumka. 1968.
Kuprukhin, A.A., Optimization of the Heat Shield of Hypersonic Space Vehicles by Variation of Its Catalytic and Emission Properties, Cand. Sci. Dissertation, Moscow, 2010.
Rebillat, F., Advances in Self-Healing Ceramic Matrix Composites, Elsevier ltd., 2014, pp. 369–409.
Kolovertnov, D.V., Oxidation Processes of Glass-Ceramic Composites Based on Zirconium Boride and Silicon-Containing Compounds, Cand. Sci. Dissertation, St. Petersburg, 2012.
Sevasty’anov, V.G., Simonenko, E.P., Gordeev, A N., et al., Russ. J. Inorg. Chem., 2014, vol. 59, no. 11, pp. 1298–1311.
Sevasty’anov, V.G., Simonenko, E.P., Gordeev, A.N., et al., Russ. J. Inorg. Chem., 2014, vol. 59, no. 12, pp. 1361–1382.
Kablov, E.N., Aviats. Mater. Tekhnol., 2012, no. S, pp. 7–17.
Maksimov, V. G., Basargin, O. V., Shcheglova, T. M., and Nikitina, V.Yu., Trudy VIAM, 2013, no. 6, paper 04 (viam-works.ru).
Kessel, H.U. and Hennicke, J., Interceram, 2007, vol. 56, no. 3, pp. 164–166.
Sorokin, O.Yu., Grashchenkov, D.V., Solntsev, S.St., and Evdokimov, S.A., Trudy VIAM, 2014, no. 6, paper. 08 (viam-works.ru).
Khasanov, O.L., Dvilis, E.S., and Bikbaeva, Z.G., Metody kompaktirovaniya i konsolidatsii nanostrukturnykh materialov (Methods for Compaction and Consolidation of Nanostructured Materials), Tomsk: Tomsk. Politekhn. Univ., 2008.
Annenkov, Yu.M., Akarakchin, S.A., and Ivashutenko A.S., Butlerovskie Soobshch., 2012, vol. 30, no. 4, pp. 74–78.
Khasanov, O.L., Dvilis, E.S., Khasanov, A.O., et al., Izv. Tomsk. Politekhn. Univ., 2012, vol. 320, no. 2, pp. 58–62.
Khasanov, O.L., Dvilis, E.S., Khasanov, A.O., et al., Izv. Vyssh. Uchebn. Zaved, Fiz., 2012, vol. 55, no. 52, pp. 270–275.
Blagoveshchenskii, Yu.V., Boldin, M.S., Isaeva, N.V., and Kotkov, D.N., Nauch. Vedomosti., Ser.: Mat., Fiz., 2011, no. 11(106), issue 23, pp. 151–158.
Popil’skii, R.Ya. and Pivinskii, Yu.E., Pressovanie poroshkovykh keramicheskikh mass (Compaction of Powdered Ceramic Masses), Moscow: Metallurgiya, 1983.
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Original Russian Text © D.V. Grashchenkov, O.Yu. Sorokin, Yu.E. Lebedeva, M. L. Vaganova, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 3, pp. 379–386.
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Grashchenkov, D.V., Sorokin, O.Y., Lebedeva, Y.E. et al. Specific features of sintering of HfB2-based refractory ceramic by hybrid spark plasma sintering. Russ J Appl Chem 88, 386–393 (2015). https://doi.org/10.1134/S1070427215030040
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DOI: https://doi.org/10.1134/S1070427215030040