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Effect of alkali metal oxides on the selectivity of carbon monoxide conversion to give hydrogen on copper-containing catalysts

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Abstract

Possibility of synthesizing aluminum-zinc-copper catalysts by mechanochemical activation of metallic copper and zinc with ammonium carbonate, followed by introduction of γ-Al2O3 and promoter additives (potassium, rubidium, and cesium carbonates), hydrothermal treatment, and calcination is demonstrated. The effect of the promoter additives and preparation conditions was studied. The activity and selectivity of the samples in the reaction of steam conversion of CO was examined. The composition of by-products formed in the course of a test reaction was determined.

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Correspondence to Yu. M. Komarov.

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Original Russian Text © Yu.M. Komarov, A.A. Il’in, N.N. Smirnov, A.P. Il’in, D.B. Babaikin, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 1, pp. 31–35.

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Komarov, Y.M., Il’in, A.A., Smirnov, N.N. et al. Effect of alkali metal oxides on the selectivity of carbon monoxide conversion to give hydrogen on copper-containing catalysts. Russ J Appl Chem 86, 27–31 (2013). https://doi.org/10.1134/S1070427213010060

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  • DOI: https://doi.org/10.1134/S1070427213010060

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