Abstract
Possibility of synthesizing aluminum-zinc-copper catalysts by mechanochemical activation of metallic copper and zinc with ammonium carbonate, followed by introduction of γ-Al2O3 and promoter additives (potassium, rubidium, and cesium carbonates), hydrothermal treatment, and calcination is demonstrated. The effect of the promoter additives and preparation conditions was studied. The activity and selectivity of the samples in the reaction of steam conversion of CO was examined. The composition of by-products formed in the course of a test reaction was determined.
Similar content being viewed by others
References
Proizvodstvo ammiaka (Manufacture of Ammonium), Semenov, V.P., Ed., Moscow: Khimiya, 1985.
Komarov, Yu.M., Smirnov, N.N., and Il’in, A.P., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2006, no. 7, p. 48.
Komarov, Yu.M., Cand. Sci. Dissertation, Ivanovo, 2006.
Il’in, A.P., Smirnov, N.N., and Il’in, A.A., Kinet. Kataliz, 2006, vol. 47, no. 6, p. 929.
RF Patent 2358804.
Sapamyan, N.A., Danielyan, N.G., and Kaplakyan, A.N., Mekhanokhimicheskii sintez (Mechanochemical Synthesis), Vladivostok: Dal’nevostochn. Univ., 1990, p. 214.
Ketchik, S.V., Plyasova, L.M., Yur’eva, T.M., et al., Izv. Sib. Otd. Akad. Nauk SSSR, Khimiya, 1984, issue 1, no. 2, p. 36.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Yu.M. Komarov, A.A. Il’in, N.N. Smirnov, A.P. Il’in, D.B. Babaikin, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 1, pp. 31–35.
Rights and permissions
About this article
Cite this article
Komarov, Y.M., Il’in, A.A., Smirnov, N.N. et al. Effect of alkali metal oxides on the selectivity of carbon monoxide conversion to give hydrogen on copper-containing catalysts. Russ J Appl Chem 86, 27–31 (2013). https://doi.org/10.1134/S1070427213010060
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427213010060