Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 86–91

Self-assembling in the systems МХ2–2-(7-bromo-2-oxo-5-phenyl-2,3-dihydro-1Н-1,4-benzdiazepin-1-yl)acetohydrazide–salicyl aldehyde (М = Сo, Ni, Zn; X = Cl, CH3COO)

  • A. V. Pulya
  • I. I. Seifullina
  • L. S. Skorokhod
  • V. G. Vlasenko
  • A. L. Trigub
  • Ya. V. Zubavichus
  • S. I. Levchenkov
Article

DOI: 10.1134/S1070363217010145

Cite this article as:
Pulya, A.V., Seifullina, I.I., Skorokhod, L.S. et al. Russ J Gen Chem (2017) 87: 86. doi:10.1134/S1070363217010145
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Abstract

By self-assembling in the systems MX2–2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1Н-1,4-benzdiazepin-1-yl)acetohydrazide (Hydr)–salicyl aldehyde (HSal) (М = Co, Ni, Zn; X = Cl, CH3COO) the complexes of composition [Co(HydrSal)2], [Ni(HydrSal)2], [Zn(HydrHSal)Cl2], [Zn(HydrSal)(CH3COO)(H2O)] have been synthesized. The local atomic structure of the coordination unit was determined by the method of X-ray absorption spectroscopy. Thermal stability, electroconductivity, and magnetic susceptibility of the complexes have been studied.

Keywords

coordination compounds cobalt(II) nickel(II) zinc(II) 2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1Н-1,4-benzdiazepin-1-yl)acetohydrazide salicylaldehyde 

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. V. Pulya
    • 1
  • I. I. Seifullina
    • 1
  • L. S. Skorokhod
    • 1
  • V. G. Vlasenko
    • 2
  • A. L. Trigub
    • 3
  • Ya. V. Zubavichus
    • 3
  • S. I. Levchenkov
    • 4
  1. 1.I.I. Mechnikov Odessa National UniversityOdessaUkraine
  2. 2.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  3. 3.Russian Scientific Center “Kurchatov Institute”MoscowRussia
  4. 4.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia

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