Russian Journal of General Chemistry

, Volume 85, Issue 12, pp 2759–2764

Biacetyl monooxime ferrocenoylhydrazone and its complexing properties

  • A. N. Morozov
  • L. D. Popov
  • E. A. Raspopova
  • S. I. Levchenkov
  • I. N. Shcherbakov
  • D. S. Samorodnyaya
  • V. A. Kogan
Article

DOI: 10.1134/S1070363215120178

Cite this article as:
Morozov, A.N., Popov, L.D., Raspopova, E.A. et al. Russ J Gen Chem (2015) 85: 2759. doi:10.1134/S1070363215120178
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Abstract

Biacetyl monooxime ferrocenoylhydrazone has been synthesized and studied by 1H NMR, IR, and electronic spectroscopy. The electronic absorption spectrum of the title compound in the UV and visible regions has been found to depend on the solvent polarity and pH. Most favorable structures of the hydrazone in solution and gas phase have been determined by quantum chemical calculations. The complexing ability of biacetyl monooxime ferrocenoylhydrazone toward copper(II), nickel(II), and zinc(II) ions has been estimated.

Keywords

ferrocenoylhydrazones electronic spectroscopy tautomerism density functional theory complex formation 

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • A. N. Morozov
    • 1
  • L. D. Popov
    • 1
  • E. A. Raspopova
    • 1
  • S. I. Levchenkov
    • 2
  • I. N. Shcherbakov
    • 1
  • D. S. Samorodnyaya
    • 1
  • V. A. Kogan
    • 1
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia

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