Russian Journal of General Chemistry

, Volume 85, Issue 10, pp 2338–2347

Chemical and electrochemical synthesis, local atomic structure, and properties of copper(II), cobalt(II), and nickel(II) complexes with azo compounds containing an additional azo group in the para or ortho position of the amine fragment

  • A. S. Burlov
  • S. A. Mashchenko
  • V. G. Vlasenko
  • E. D. Garnovskaya
  • Ya. V. Zubavichus
  • S. I. Levchenkov
  • Yu. S. Kurinnaya
Article

DOI: 10.1134/S1070363215100199

Cite this article as:
Burlov, A.S., Mashchenko, S.A., Vlasenko, V.G. et al. Russ J Gen Chem (2015) 85: 2338. doi:10.1134/S1070363215100199

Abstract

New copper(II), cobalt(II), and nickel(II) complexes with 1-[4-(phenydiazenyl)phenyldiazenyl]-naphthalen-2-ol and 1-[4-methyl-2-(4-methylphenyldiazenyl)phenyldiazenyl]naphthalen-2-ol have been synthesized by chemical and electrochemical methods and characterized by IR, 1H NMR, and X-ray absorption spectroscopy, as well as by magnetochemistry and quantum chemical calculations. Coordination of the nitrogen atom in the additional azo group to the metal ion is determined by its position (ortho or para) and metal nature.

Keywords

azo compounds metal chelates X-ray absorption spectroscopy local atomic structure magnetochemistry quantum chemical calculations 

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • A. S. Burlov
    • 1
  • S. A. Mashchenko
    • 1
  • V. G. Vlasenko
    • 2
  • E. D. Garnovskaya
    • 1
  • Ya. V. Zubavichus
    • 3
  • S. I. Levchenkov
    • 4
  • Yu. S. Kurinnaya
    • 1
  1. 1.Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia
  2. 2.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  3. 3.“Kurchatov Institute” National Research CenterMoscowRussia
  4. 4.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia

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