Russian Journal of General Chemistry

, Volume 85, Issue 8, pp 1902–1909

Physico-chemical study of the complex formation between 2-(tosylamino)benzaldehyde bishydrazones and transition metal ions

  • L. D. Popov
  • Yu. P. Tupolova
  • S. I. Levchenkov
  • A. A. Tsaturyan
  • V. V. Lukov
  • S. A. Borodkin
  • I. N. Shcherbakov
  • A. S. Burlov
  • A. A. Zubenko
  • I. V. Pankov
Article

DOI: 10.1134/S1070363215080186

Cite this article as:
Popov, L.D., Tupolova, Y.P., Levchenkov, S.I. et al. Russ J Gen Chem (2015) 85: 1902. doi:10.1134/S1070363215080186
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Abstract

New 2-(tosylamino)benzaldehyde bishydrazones and their complexes with copper(II) and zinc(II) have been synthesized. Structure and properties of the prepared compounds have been studied by means of IR and 1H NMR spectroscopy as well as magnetochemistry. Quantum-chemical simulation of the relative stability of tautomeric forms of the bishydrazones has been performed.

Keywords

bishydrazone quantum-chemical simulation coordination compound magnetochemistry 

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • L. D. Popov
    • 1
  • Yu. P. Tupolova
    • 1
  • S. I. Levchenkov
    • 2
  • A. A. Tsaturyan
    • 1
  • V. V. Lukov
    • 1
  • S. A. Borodkin
    • 1
  • I. N. Shcherbakov
    • 1
  • A. S. Burlov
    • 3
  • A. A. Zubenko
    • 4
  • I. V. Pankov
    • 1
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific Center of Russian Academy of SciencesRostov-on-DonRussia
  3. 3.Research Institute of Physical and Organic Chemistry of Southern Federal UniversityRostov-on-DonRussia
  4. 4.North-Caucasian Zonal Research Veterinary InstituteNovocherkasskRussia

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