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Aryl(hetaryl)-containing gem-cyanonitroethenes: Synthesis, structure, and reactions with 2,3-dimethyl-1,3-butadiene

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Abstract

Methods of aryl(hetaryl)-substituted gem-cyanonitroethenes preparation are summarized, and the products structure elucidation by means of 1H, 13C NMR, IR, and UV spectroscopy methods is discussed. E-Configuration of the compounds obtained has been proved. Reaction of the studied gem-cyanonitroethenes with 2,3-dimethyl-1,3-butadiene affords the diene synthesis adducts–6-aryl(hetaryl)-3,4-dimethyl-1-nitro-1-cyano- 3-cyclohexenes.

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Correspondence to R. I. Baichurin.

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Original Russian Text © R.I. Baichurin, N.I. Aboskalova, E.V. Trukhin, V.M. Berestovitskaya, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 8, pp. 1288–1297.

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Baichurin, R.I., Aboskalova, N.I., Trukhin, E.V. et al. Aryl(hetaryl)-containing gem-cyanonitroethenes: Synthesis, structure, and reactions with 2,3-dimethyl-1,3-butadiene. Russ J Gen Chem 85, 1845–1854 (2015). https://doi.org/10.1134/S1070363215080101

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