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Furan-containing gem-bromonitroethenes: Synthesis and reaction with morpholine

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Abstract

The first time the representative of furan-containing gem-bromonitroethenes 5-nitro-2-(2-bromo-2-nitro-ethenyl)furan was synthesized by bromination of 5-nitro-2-(2-nitroethenyl)furan followed by dehydrohalogenation of the dibromide. Morpholine adducts of the synthesized β-substituted gem-bromonitroethene and its analog with a 5-bromo-2-furyl substituent were obtained. The structures of the gem-bromonitroethenes and aza adducts were characterized by spectral methods (IR, UV, 1H, and 13C-{1H} NMR, including 1H-13C HMQC and HMBC).

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Authors and Affiliations

  1. Herzen State Pedagogical University, nab. reki Moiki 48, St. Petersburg, 191186, Russia

    S. S. Eliseenko, S. V. Makarenko & V. M. Berestovitskaya

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  1. S. S. Eliseenko
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  2. S. V. Makarenko
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  3. V. M. Berestovitskaya
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Correspondence to S. S. Eliseenko.

Additional information

Original Russian Text © S.S. Eliseenko, S.V. Makarenko, V.M. Berestovitskaya, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 6, pp. 957–963.

To the memory of Prof. B.I. Ionin

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Eliseenko, S.S., Makarenko, S.V. & Berestovitskaya, V.M. Furan-containing gem-bromonitroethenes: Synthesis and reaction with morpholine. Russ J Gen Chem 85, 1424–1430 (2015). https://doi.org/10.1134/S1070363215060110

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  • DOI: https://doi.org/10.1134/S1070363215060110

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