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Synthesis of organophosphorus compounds based on the reaction of elemental phosphorus with proton-donor reagents

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Abstract

Reaction of elemental (white) phosphorus with proton-donor reagents has been studied. The following organophosphorus compounds containing P-O and P-S bonds have been synthesized: metal hypophosphites and phosphites, and ammonium salts of O,O′-diesters of dithiophosphoric, S,S′-diphenyldithiophosphoric, S,S′-dialkyltetrathiophosphoric, O,O′-alkylidenedithiophosphoric acids, and octathiotetraphosphetane. The reaction products include highly efficient inhibitors of steel corrosion with carbonic acid and hydrogen sulfide as well as compounds showing fungicide, anticancer, and anti-inflammatory activity.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, Tatarstan, 420088, Russia

    E. K. Badeeva, E. V. Platova & E. S. Batyeva

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  1. E. K. Badeeva
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  2. E. V. Platova
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  3. E. S. Batyeva
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Correspondence to E. K. Badeeva.

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Original Russian Text © E.K. Badeeva, E.V. Platova, E.S. Batyeva, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 2, pp. 219–228.

To the 80th Anniversary of B.I. Ionin

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Badeeva, E.K., Platova, E.V. & Batyeva, E.S. Synthesis of organophosphorus compounds based on the reaction of elemental phosphorus with proton-donor reagents. Russ J Gen Chem 85, 392–401 (2015). https://doi.org/10.1134/S1070363215020085

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  • DOI: https://doi.org/10.1134/S1070363215020085

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