Abstract
2-N-Tosylaminobenzaldehyde ferrocenoylhydrazone was synthesized. The crystal structure of the hydrazone was shown to include two independent molecules differing in mutual orientation of the tosyl and ferrocene fragments. Quantum-chemical simulation of the hydrazone tautomerism was performed. Its complexes with Cu(II), Ni(II), Zn(II), and Cd(II) were synthesized and investigated.
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Original Russian Text © L.D. Popov, A.N. Morozov, E.A. Raspopova, S.I. Levchenkov, I.N. Shcherbakov, A.S. Burlov, G.G. Aleksandrov, V.A. Kogan, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 1, pp. 135–143.
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Popov, L.D., Morozov, A.N., Raspopova, E.A. et al. Ferrocenoylhydrazone of 2-N-tosylaminobenzaldehyde: Structure, properties, and complexing ability. Russ J Gen Chem 85, 126–134 (2015). https://doi.org/10.1134/S1070363215010223
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DOI: https://doi.org/10.1134/S1070363215010223