Russian Journal of General Chemistry

, Volume 85, Issue 1, pp 126–134

Ferrocenoylhydrazone of 2-N-tosylaminobenzaldehyde: Structure, properties, and complexing ability

  • L. D. Popov
  • A. N. Morozov
  • E. A. Raspopova
  • S. I. Levchenkov
  • I. N. Shcherbakov
  • A. S. Burlov
  • G. G. Aleksandrov
  • V. A. Kogan
Article

DOI: 10.1134/S1070363215010223

Cite this article as:
Popov, L.D., Morozov, A.N., Raspopova, E.A. et al. Russ J Gen Chem (2015) 85: 126. doi:10.1134/S1070363215010223

Abstract

2-N-Tosylaminobenzaldehyde ferrocenoylhydrazone was synthesized. The crystal structure of the hydrazone was shown to include two independent molecules differing in mutual orientation of the tosyl and ferrocene fragments. Quantum-chemical simulation of the hydrazone tautomerism was performed. Its complexes with Cu(II), Ni(II), Zn(II), and Cd(II) were synthesized and investigated.

Keywords

ferrocenoylhydrazones electronic spectroscopy tautomerism X-ray diffraction analysis density functional theory complex formation 

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • L. D. Popov
    • 1
  • A. N. Morozov
    • 1
  • E. A. Raspopova
    • 1
  • S. I. Levchenkov
    • 2
  • I. N. Shcherbakov
    • 1
  • A. S. Burlov
    • 1
  • G. G. Aleksandrov
    • 3
  • V. A. Kogan
    • 1
  1. 1.Chemical DepartmentSouthern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific Center of the Russian Academy of SciencesRostov-on-DonRussia
  3. 3.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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