Russian Journal of General Chemistry

, Volume 85, Issue 1, pp 104–110

Synthesis, structure, and properties of the product formed in the reaction of ortho-diphenylphosphinobenzaldehyde and N-tosyl-1,2-phenylenediamine

  • L. D. Popov
  • S. A. Borodkin
  • M. E. Kletskii
  • O. N. Burov
  • P. G. Morozov
  • I. N. Shcherbakov
  • Yu. P. Tupolova
  • L. I. Etmetchenko
  • A. V. Tkachuk
  • V. A. Kogan
Article

DOI: 10.1134/S1070363215010181

Cite this article as:
Popov, L.D., Borodkin, S.A., Kletskii, M.E. et al. Russ J Gen Chem (2015) 85: 104. doi:10.1134/S1070363215010181
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Abstract

Interaction of ortho-diphenylphosphinobenzaldehyde with N-tosyl-1,2-phenylenediamine afforded the product of intramolecular Wittig reaction, N-{2-[2-(Diphenylphosphoryl)benzylamino]phenyl}-4-methylbenzenesulfonamide. Its structure was established on the basis of IR, 1H NMR, 13C NMR, and 2D 1H NMR (COSY) spectroscopy. Reaction mechanism was studied by means of quantum chemistry DFT method. Complexforming property of the obtained diphenylphosphine oxide was investigated.

Keywords

aromatic phosphine oxide NMR spectroscopy quantum chemical DFT calculations metal complexes 

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • L. D. Popov
    • 1
  • S. A. Borodkin
    • 1
  • M. E. Kletskii
    • 1
  • O. N. Burov
    • 1
  • P. G. Morozov
    • 1
  • I. N. Shcherbakov
    • 1
  • Yu. P. Tupolova
    • 1
  • L. I. Etmetchenko
    • 2
  • A. V. Tkachuk
    • 1
  • V. A. Kogan
    • 1
  1. 1.Chemical FacultySouthern Federal UniversityRostov-on-DonRussia
  2. 2.Scientific Research Institute of Physical and Organic ChemistrySouth Federal UniversityRostov-on-DonRussia

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