Russian Journal of General Chemistry

, Volume 83, Issue 10, pp 1928–1936

Transition metal complexes with 2,6-Di-tert-butyl-p-quinone 1′-phthalazinylhydrazone

  • S. I. Levchenkov
  • I. N. Shcherbakov
  • L. D. Popov
  • S. N. Lyubchenko
  • K. Yu. Suponitskii
  • A. A. Tsaturyan
  • S. S. Beloborodov
  • V. A. Kogan
Article

DOI: 10.1134/S1070363213100216

Cite this article as:
Levchenkov, S.I., Shcherbakov, I.N., Popov, L.D. et al. Russ J Gen Chem (2013) 83: 1928. doi:10.1134/S1070363213100216
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Abstract

2,6-Di-tert-butyl-p-quinone 1′-phthalazinylhydrazone (HL) was synthesized. Quantum-chemical calculations of the energy of possible tautomeric forms of the hydrazone were performed. The complexes of Zn(II), Hg(II), Ni(II), and Cu(II) of ML2 composition were obtained and studied. The structure of the NiL2 complex was established by XRD. It was shown by DFT-D3 calculations that the cis-structure of the complex is stabilized due to the interligand dispersion interaction.

Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • S. I. Levchenkov
    • 1
  • I. N. Shcherbakov
    • 2
  • L. D. Popov
    • 2
  • S. N. Lyubchenko
    • 2
  • K. Yu. Suponitskii
    • 3
  • A. A. Tsaturyan
    • 2
  • S. S. Beloborodov
    • 2
  • V. A. Kogan
    • 2
  1. 1.Southern Scientific Center of the Russian Academy of SciencesRostov-on-DonRussia
  2. 2.Department of ChemistrySouthern Federal UniversityRostov-on-DonRussia
  3. 3.Nesmeyanov Institute of Organoelemental CompoundsRussian Academy of SciencesMoscowRussia

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