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Synthesis of new spiropyranes and study of the effect of the nature of substituents on their photochromism and complexation

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Abstract

A series of new hydrazones based on 3,3-dimethyl-7-hydroxy-8-formyl-[2H]-1-benzopyran-2,1-[2]-oxaindane] with the substituents of different nature in the hydrazone moiety was synthesized. A comparative study of photochromism and complexation of the synthesized spiropyrans with a number of metal cations was carried out. Spectral and kinetic differences in photochromism and complexation of these compounds were revealed.

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References

  1. Guglielmetti, R., Photochromism. Molecules and Systems, Amsterdam: Elsevier, 1990, p. 314.

    Google Scholar 

  2. Bertelson, R.S., Organic Photochromic and Thermochromic Compounds, New York: Plenum Press, 1999, vol. 1, p. 11.

    Google Scholar 

  3. Berckovic, G. and Krongausz, V., Weiss V, Chem. Rev., 2000, vol.100, p. 1741.

    Article  Google Scholar 

  4. Minkin, V.I., Chem. Rev., 2004, vol. 104, p. 2751.

    Article  CAS  Google Scholar 

  5. Bulanov, A.O., Popov, L.D., Shcherbakov, I.N., Kogan, V.A., Barachevsky, V.A., Lukov, V.V., Borisenko, S.N., and Tkachenko, Yu.N., Spectrochim. Acta, Part A, 2008, vol. 71, p. 1146.

    Article  Google Scholar 

  6. Popov, L.D., Shcherbakov, I.N., Bulanov, A.O., Valova, T.M., and Barachevskii, V.A., Izv. Akad. Nauk, Ser. Khim., 2009, no. 12, p. 2340.

    Google Scholar 

  7. Bulanov, A.O., Luk’yanov, B.S., Kogan, V.A., and Lukov, V.V., Koord. Khim., 2003, vol. 29, no. 9, p. 709.

    Google Scholar 

  8. Luk’yanov, B.S., Nivorozhkin, L.E., and Minkin, V.I., Khim. Geterotsikl. Soed., 1990, p. 1700.

    Google Scholar 

  9. Luk’yanov, B.S., Nivorozhkin, L.E., and Minkin, V.I., Khim. Geterotsikl. Soed., 1993, p. 176.

    Google Scholar 

  10. Bulanov, A.O., Safoklov, B.B., Luk’yanov, B.S., Tkachev, V.V., Minkin, V.I., Aldoshin, S.M., and Alekseenko, Yu.S., Khim. Geterotsikl. Soed., 2003, p. 350.

    Google Scholar 

  11. Bulanov, A.O., Luk’yanov, B.S., Kogan, V.A., Stankevich, N.V., and Lukov, V.V., Koord. Khim., 2002, vol. 28, p. 49.

    Google Scholar 

  12. Alekseenko, Yu.S., Bulanov, A.O., Sayapin, Yu.A., Alekseenko, A.S., Luk’yanov, B.S., and Safoklov, B.B., Khim. Geterotsikl. Soed., 2002, p. 1308.

    Google Scholar 

  13. Barachevskii, V.A., Kobeleva, O.I., Valova, T.M., Popov, L.D., Shcherbakov, I.N., Bulanov, A.O., and Kogan, V.A., Ross. Khim. Zh., 2009, vol.53, no. 1, p.110.

    CAS  Google Scholar 

  14. Baggett, N., Foster, A.B., Haines, A.H., and Stacy, M., J. Chem. Soc., 1960, no. 9, p. 3528.

    Google Scholar 

  15. Bulanov, A.O., Shcherbakov, I.N., Popov, L.D., Shasheva, E.Y., Belikov, P.A., and Starikova, Z.A., Acta. Cryst., C, 2011, vol. 67, p. 85.

    Article  Google Scholar 

  16. Bulanov, A.O., Shcherbakov, I.N., Tupolova, Yu.P., Popov, L.D., Lukov, V.V., Kogan, V.A., and Belikov, P.A., Acta. Cryst., C, 2009, vol.65, p. 618.

    Article  Google Scholar 

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Correspondence to L. D. Popov.

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Original Russian Text © L.D. Popov, A.O. Bulanov, E.A. Raspopova, A.N. Morozov, I.N. Scherbakov, O.I. Kobeleva, T.M. Valova, V.A. Barachevskii, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 6, pp. 980–985.

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Popov, L.D., Bulanov, A.O., Raspopova, E.A. et al. Synthesis of new spiropyranes and study of the effect of the nature of substituents on their photochromism and complexation. Russ J Gen Chem 83, 1111–1116 (2013). https://doi.org/10.1134/S1070363213060182

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  • DOI: https://doi.org/10.1134/S1070363213060182

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