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Spectroscopic study of interaction of 1H-1,2,4-triazoline-3-thione with molecular iodine

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Abstract

The formation by 1H-1,2,4-triazoline-3-thiones in dilute chloroform solution of n-σ*-complex with molecular iodine of the composition C2H2N3S·I2 was studied by electronic spectroscopy in the UV and visible regions (log β = 2.14±0.05). By the XRD method the crystal and molecular structure of the product of chemical interaction of the thione with molecular iodine in ethanol, 1,2-di(1H-1,2,4-triazol-3-yl) disulfide, was determined.

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Authors and Affiliations

  1. Southern Federal University, ul. Zorge 7, Rostov-on-Don, 344090, Russia

    M. S. Chernovyants, N. V. Aleshina & I. N. Shcherbakov

  2. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    Z. A. Starikova

Authors
  1. M. S. Chernovyants
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  2. N. V. Aleshina
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  3. I. N. Shcherbakov
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  4. Z. A. Starikova
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Correspondence to M. S. Chernovyants.

Additional information

Original Russian Text © M.S. Chernovyants, N.V. Aleshina, I.N. Shcherbakov, Z.A. Starikova, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 5, pp. 852–854.

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Chernovyants, M.S., Aleshina, N.V., Shcherbakov, I.N. et al. Spectroscopic study of interaction of 1H-1,2,4-triazoline-3-thione with molecular iodine. Russ J Gen Chem 83, 986–988 (2013). https://doi.org/10.1134/S1070363213050186

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  • DOI: https://doi.org/10.1134/S1070363213050186

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