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Ion-selective liquid electrodes: Problems of description and experimental determination of selectivity

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Abstract

Current state of selectivity theory for liquid-membrane ion-selective electrodes was considered. Analytical expressions for the selectivity coefficients of electrodes based on liquid ion exchangers, neutral carriers, and charged carriers were obtained using phase boundary potential model. The reasons responsible for the dependence of experimentally determined selectivity coefficients on the determination conditions are discussed. The main ways for the electrode design optimization providing dramatic improvement of the selectivity are considered.

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Authors and Affiliations

  1. Scientific Research Institute of Physicochemical Problems, Belarus State University, ul. Leningradskaya 14, Minsk, 220030, Belarus

    V. V. Egorov

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  1. V. V. Egorov
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Correspondence to V. V. Egorov.

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Original Russian Text © V.V. Egorov, 2008, published in Rossiiskii Khimicheskii Zhurnal, 2008, Vol. 52, No. 2, pp. 37–51

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Egorov, V.V. Ion-selective liquid electrodes: Problems of description and experimental determination of selectivity. Russ J Gen Chem 78, 2455–2471 (2008). https://doi.org/10.1134/S107036320812027X

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