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Electrochemical synthesis, properties, and structure of copper, nickel, and cobalt complexes of tridentate tosylamino-functionalized mercaptopyrazole Schiff base

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Abstract

Copper, nickel, and cobalt complexes of the N,N,S-tridentate tosylamino-functionalized mercaptopyrazole Schiff base were obtained by an electrochemical method. The structure and composition of the metal chelates were characterized by C, H, N elemental analysis data and IR and 1H NMR spectroscopy. More data on the structures of the complexes were obtained by magnetochemical and X-ray absorption spectroscopy measurements. The mononuclear structure of the copper(II) complex was confirmed by X-ray diffraction (CIF file CCDC no. 1473320).

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References

  1. Cassoux, P., Valade, L., and Fabre, P.-L., Comprehensive Coordination Chemistry II, Lever A.B.P., Ed., vol. 1, 2003, p. 761.

    Article  Google Scholar 

  2. Rodríguez, A. and García-Vazquez, J.A., Coord. Chem. Rev., 2015, vol. 303, p. 42.

    Article  Google Scholar 

  3. Uraev, A.I., Vasilchenko, I.S., Ikorskii, V.N., et al., Mendeleev Commun., 2005, vol. 15, no. 4, p. 133.

    Article  Google Scholar 

  4. Bernal, M., García-Vazquez, J.A., Romero, J., et al., Inorg. Chim. Acta, 1999, vol. 295, no. 1, p. 39.

    Article  CAS  Google Scholar 

  5. Garnovskii, A.D., Burlov, A.S., Garnovskii, D.A., et al., Polyhedron, 1999, vol. 18, no. 7, p. 1985.

    Google Scholar 

  6. Sanmartín, J., Novio, F., García-Deibe, A.M., et al., Eur. J. Inorg. Chem., 2008, no. 10, p. 1719.

    Article  Google Scholar 

  7. Garnovskii, D.A., Guedes da Silva, M.F.C., Kopylovich, M.N., et al., Polyhedron, 2003, vol. 22, no. 10, p. 1335.

    Article  CAS  Google Scholar 

  8. Garnovskii, D.A., Sadikov, G.G., Antsyshkina, A.S., et al., Cryst. Rep., 2003, vol. 48. no. 3., p. 426.

    Article  CAS  Google Scholar 

  9. Sousa-Pedrares, A., Viqueira, J.A., Antelo, J., et al., Eur. J. Inorg. Chem., 2011, no. 14, p. 2273.

    Article  Google Scholar 

  10. Garnovskii, D.A., Antsyshkina, A.S., Sadikov, G.G., et al., Russ. J. Inorg. Chem., 2014, vol. 59, no. 5, p. 431.

    Article  CAS  Google Scholar 

  11. Garnovskii, D.A., Antsyshkina, A.S., Makarova, N.I., et al., Russ. J. Inorg. Chem., 2015, vol. 60. no. 12, p. 1528.

    Article  CAS  Google Scholar 

  12. Kvitko, I.Ya., Zh. Org. Khim., 1969, vol. 5. no. 7, p. 1685.

    CAS  Google Scholar 

  13. Malick, W.U. and Sharma, T.S., J. Ind. Chem. Soc., 1970, vol. 47, no. 2, p. 167.

    Google Scholar 

  14. Tuck, D.G., Pure Appl. Chem., 1979, vol. 51, no. 10, p. 2005.

    Article  CAS  Google Scholar 

  15. Chernyshov, A.A., Veligzhanin, A.A., Zubavichus, Y.V., et al., Nucl. Instr. Meth. Phys. Res. A, 2009, vol. 603, p. 95.

    Article  CAS  Google Scholar 

  16. Kochubei, D.I., Babanov, Yu.A., Zamaraev, K.I., et al., Rentgenospektral’nyi metod izucheniya struktury amorfnykh tel: EXAFS-spektroskopiya (X-Ray Spectral Method for Investigation of Structures of Amorphous Bodies: EXAFS Spectroscopy), Novosibirsk Nauka, Sib. otd., 1988.

    Google Scholar 

  17. Newville, M., J. Synchrotron Rad., 2001, no. 8, p. 96.

    Article  CAS  Google Scholar 

  18. Zabinsky, S.I., Rehr, J.J., Ankudinov, A., et al., Phys. Rev. B, 1995, vol. 52, p. 2995.

    Article  CAS  Google Scholar 

  19. CrysAlisPro, Agilent Technologies. Version 1.171.36.32. Release 02-08-2013.

  20. Sheldrick, G.M., Program for the Refinement of Crystal Structure, Göttingen Univ. of Göttingen, 1997.

    Google Scholar 

  21. Kurkovskaya L.N., Shapet’ko N.N., Kvitko, I.Ya., et al., Zh. Org. Khim., 1974, vol. 10. no. 10, p. 2210.

    CAS  Google Scholar 

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Correspondence to D. A. Garnovskii.

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Original Russian Text © D.A. Garnovskii, S.I. Levchenkov, G.G. Aleksandrov, V.G. Vlasenko, Ya.V. Zubavichus, A.I. Uraev, A.S. Burlov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 3, pp. 147–155.

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Garnovskii, D.A., Levchenkov, S.I., Aleksandrov, G.G. et al. Electrochemical synthesis, properties, and structure of copper, nickel, and cobalt complexes of tridentate tosylamino-functionalized mercaptopyrazole Schiff base. Russ J Coord Chem 43, 156–163 (2017). https://doi.org/10.1134/S1070328417030010

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  • DOI: https://doi.org/10.1134/S1070328417030010

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