Electrochemical synthesis, properties, and structure of copper, nickel, and cobalt complexes of tridentate tosylamino-functionalized mercaptopyrazole Schiff base
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- Garnovskii, D.A., Levchenkov, S.I., Aleksandrov, G.G. et al. Russ J Coord Chem (2017) 43: 156. doi:10.1134/S1070328417030010
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Copper, nickel, and cobalt complexes of the N,N,S-tridentate tosylamino-functionalized mercaptopyrazole Schiff base were obtained by an electrochemical method. The structure and composition of the metal chelates were characterized by C, H, N elemental analysis data and IR and 1H NMR spectroscopy. More data on the structures of the complexes were obtained by magnetochemical and X-ray absorption spectroscopy measurements. The mononuclear structure of the copper(II) complex was confirmed by X-ray diffraction (CIF file CCDC no. 1473320).