Binuclear dysprosium(III) complex with 2,6-diformyl-4-tert-butylphenol bisphthalazinylhydrazone: Crystal structure and magnetic properties
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- Levchenkov, S.I., Popov, L.D., Beloborodov, S.S. et al. Russ J Coord Chem (2015) 41: 823. doi:10.1134/S1070328415120040
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The Dy(III) binuclear complex with N4O-donor 2,6-diformyl-4-tert-butylphenol bis-1′-phthalazinylhydrazone (H3L) of the composition [Dy2(H2L)3](NO3)3 · 3C2H5OH (CIF file CCDC 1048418) is synthesized and structurally characterized. In the complex cation [Dy2(H2L)3]3+, ligands H2L− form a three-blade helix around the Dy(III) ions. Both right-side (Δ configuration) and left-side (Λ) helicates are presented in crystal in an equimolar ratio. The magnetic properties of the complex are studied.