Russian Journal of Coordination Chemistry

, Volume 41, Issue 6, pp 376–386

Metal complexes of azomethine compounds bearing an azo group in the amine fragment: Syntheses, structures, and properties

  • A. S. Burlov
  • S. A. Mashchenko
  • V. G. Vlasenko
  • K. A. Lysenko
  • A. S. Antsyshkina
  • G. G. Sadikov
  • V. S. Sergienko
  • Yu. V. Koshchienko
  • Ya. V. Zubavichus
  • A. I. Uraev
  • D. A. Garnovskii
  • E. V. Korshunova
  • S. I. Levchenkov
Article

DOI: 10.1134/S1070328415060019

Cite this article as:
Burlov, A.S., Mashchenko, S.A., Vlasenko, V.G. et al. Russ J Coord Chem (2015) 41: 376. doi:10.1134/S1070328415060019

Abstract

New complexes of Cu(II), Co(II), Ni(II), and Zn(II) with 1-phenyl-3-methyl-4-(4-phenylazophenylaminomethylene)pyrazol-5-one (HL1) and 1-phenyl-3-methyl-4-[4-methyl-2-(4-methylphenylazo)phenylaminomethylene]pyrazol-5-one (HL2) are synthesized using chemical and electrochemical methods and characterized by IR spectroscopy, 1H NMR spectroscopy, X-ray absorption spectroscopy, X-ray diffraction analysis, and magnetic measurements. All complexes are mononuclear. The structures of HL2 and related cobalt complex are determined by X-ray diffraction analysis (CIF files CCDC nos. 1028957 and 1035847, respectively).

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • A. S. Burlov
    • 1
  • S. A. Mashchenko
    • 1
  • V. G. Vlasenko
    • 2
  • K. A. Lysenko
    • 3
  • A. S. Antsyshkina
    • 4
  • G. G. Sadikov
    • 4
  • V. S. Sergienko
    • 4
  • Yu. V. Koshchienko
    • 1
  • Ya. V. Zubavichus
    • 3
    • 5
  • A. I. Uraev
    • 1
  • D. A. Garnovskii
    • 1
    • 6
  • E. V. Korshunova
    • 1
  • S. I. Levchenkov
    • 6
  1. 1.Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia
  2. 2.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  3. 3.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia
  4. 4.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  5. 5.Kurchatov Institute Russian Research CenterMoscowRussia
  6. 6.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia

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