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Anions-induced assembly: Structures and luminescent properties

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Abstract

Self-assembly of a multidentate ligand containing pyridyl groups, namely, 6-phenyl-4-(4′-[2-(2-naphthalene)ethenyl]phenyl)-2,2′-bipyridine (L) with corresponding zinc(II) salts, affords a series of coordination complexes, ZnLI2 (I), [ZnLCl2]2 · 2CH2Cl2 (II), ZnLBr2 (III). Complexes I and II were characterized by single crystal X-ray diffraction (CIF files CCDC nos. 943273 (I), 944798 (II)). In complex I, the π-π stacking and C-H⋯π interactions based on the pyridyl group constructed the 1D and 2D structures. While in complex II, various weak interactions including hydrogen bonds (C-H⋯Cl and C-H⋯π) played significant roles in the final supramolecular structures. The luminescent properties of ligand and the complexes were investigated. The results reveal that different anions have shown a great influence on both the molecular structures and luminescent properties of the complexes.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei, 230601, P.R. China

    N. Zhang, D. L. Xu, J. H. Yu, M. D. Yang & H. P. Zhou

  2. Department of Civil Engineering, Anhui Communication Vocational and Technical College, Hefei, 230051, P.R. China

    L. P. Wang

  3. Department of Chemistry, Huainan Normal College, Huainan, 232001, P.R. China

    Q. Y. Zhu

Authors
  1. N. Zhang
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  2. L. P. Wang
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  3. D. L. Xu
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  4. J. H. Yu
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  5. M. D. Yang
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  6. Q. Y. Zhu
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  7. H. P. Zhou
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Correspondence to H. P. Zhou.

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Zhang, N., Wang, L.P., Xu, D.L. et al. Anions-induced assembly: Structures and luminescent properties. Russ J Coord Chem 40, 711–717 (2014). https://doi.org/10.1134/S1070328414100121

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  • DOI: https://doi.org/10.1134/S1070328414100121

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