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Synthesis and crystal structure of a novel tri-nuclear nickel(II) complex derived from N,N′-(2-hydroxypropane-1,3-diyl)bis(salicylaldimine)

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Abstract

A novel tri-nuclear nickel(II) complex, [Ni3L2(μ2-η1:η1-OAc)2(μ1-η1:η0-OAc)2] · H2O (H2L is N,N′-(2-hydroxypropane-1,3-diyl)-bis(salicylaldimine), was prepared. The complex was characterized by elemental analysis, IR spectra, and single crystal X-ray determination (CIF file CCDC no. 993163). Crystal of the complex crystallizes in the monoclinic space group P21/n. The unit cell parameters: a = 12.5602(9), b = 13.2104(10), c = 15.0329(10) Å, β = 113.194(2)°, V = 2292.7(3) Å3, Z = 2, R 1 = 0.0506, wR 2 = 0.1342, S = 1.067. The complex possesses crystallographic inversion center symmetry. The Ni atoms are in octahedral coordination spheres. The Ni⋯Ni distances are 3.022(1) Å.

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Authors and Affiliations

  1. Engineering Research Center for Clean Production of Textile Printing, Ministry of Education, Wuhan Textile University, Wuhan, 430073, P.R. China

    Y. M. Cui, Q. Wang & X. J. Long

  2. School of Textile Engineering, Wuhan Textile University, Wuhan, 430073, P.R. China

    B. Zeng & W. Chen

Authors
  1. Y. M. Cui
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  2. B. Zeng
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  3. Q. Wang
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  4. X. J. Long
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  5. W. Chen
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Correspondence to W. Chen.

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Cui, Y.M., Zeng, B., Wang, Q. et al. Synthesis and crystal structure of a novel tri-nuclear nickel(II) complex derived from N,N′-(2-hydroxypropane-1,3-diyl)bis(salicylaldimine). Russ J Coord Chem 40, 768–772 (2014). https://doi.org/10.1134/S1070328414100030

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  • DOI: https://doi.org/10.1134/S1070328414100030

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