Abstract
The copper(II) and nickel(II) complexes based on bis(azomethine), which is the condensation product of 1-phenyl-3-methyl-4-formyl-5-mercaptopyrazole with 1,3-diaminopropan-2-ol, are synthesized. Bis-azomethines can form both binuclear and mononuclear complexes in which the hydroxy group is not involved in coordination. The binuclear copper(II) complexes with the acetate and pyrazolate bridges exhibit an antiferromagnetic exchange, which strength is determined by the nature of the bridge (2J = −154 and −424 cm−1, respectively). The structure parameters of the coordination spheres of the complexes are determined by X-ray absorption spectroscopy. The structure of the CHCl3 solvate of the binuclear copper(II) complex with the pyrazolate bridge is solved by X-ray diffraction analysis (CIF file CCDC 964655).
Similar content being viewed by others
References
Casellato, U., Vigato, P.A., and Vidali, M., Coord. Chem. Rev., 1977, vol. 23, no. 1, p. 31.
Suzuki, M., Furutachi, H., and Okawa, H., Coord. Chem. Rev., 2000, vols. 200–202, no. 1, p. 105.
Vigato, P.A. and Tamburini, S., Coord. Chem. Rev., 2004, vol. 248, nos. 17–20, p. 1717.
Vigato, P.A., Tamburini, S., and Bertolo, L., Coord. Chem. Rev., 2007, vol. 251, nos. 11–12, p. 1311.
Kogan, V.A., Lukov, V.V., and Shcherbakov, I.N., Russ. J. Coord. Chem., 2010, vol. 36, no. 6, p. 401.
Mazurek, W., Kennedy, B.J., Murray, K.S., et al., Inorg. Chem., 1985, vol. 24, no. 20, p. 3258.
Nishida, Y. and Kida, S., Dalton Trans., 1986, no. 12, p. 2633.
Nishida, Y. and Kida, S., Inorg. Chem., 1988, vol. 27, no. 3, p. 447.
Fallon, G.D., Markiewicz, A., Murray, K.S., and Quach, T., Chem. Commun., 1991, no. 3, p. 198.
Chou, Y.-C., Huang, S.-F., Koner, R., et al., Inorg. Chem., 2004, vol. 43, no. 9, p. 2759.
Tupolova, Yu.P., Kogan, V.A., Lukov, V.V., et al., Transition Met. Chem., 2007, vol. 32, no. 5, p. 656.
Lai, T.-C., Chen, W.-H., Lee, C.-J., et al., J. Mol. Struct., 2009, vol. 935, no. 1, p. 97.
Kou, Y., Tian, J., Li, D., et al., Dalton Trans., 2009, no. 13, p. 2374.
Popov, L.D., Tupolova, Yu.P., Lukov, V.V., et al., Inorg. Chim. Acta, 2009, vol. 362, no. 6, p. 1673.
Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., et al., Inorg. Chem. Commun., 2012, vol. 17, p. 1.
Kvitko, I.Ya. and Porai-Koshits, B.A., Zh. Org. Khim., 1969, vol. 5, no. 9, p. 1685.
SMART and SAINT. Release 5.0. Area Detector Control and Integration Software, Madison (WI, USA): Bruker AXS, 1998.
Sheldrick, G.M., SADABS. A Program for Exploiting the Redundancy of Area-Detector X-ray Data, Göttingen (Germany): Univ. of Göttingen, 1999.
Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.
Kochubei, D.I., Babanov, Yu.A., Zamaraev, K.I., et al., Rentgenospektral’nyi metod izucheniya struktury amorfnykh tel: EXAFS-spektroskopiya (X-ray Spectral Method for Investigation of the Structures of Amorphous Solids: EXAFS Spectroscopy), Novosibirsk: Nauka Sib. otd., 1988.
Newville, M., J. Synchrotron Rad., 2001, no. 8, p. 96.
Zabinski, S.I., Rehr, J.J., Ankudinov, A., and Alber, R.C., Phys. Rev., vol. 52, p. 2995.
Hennig, L., Kirmse, R., Hammerich, O., et al., Inorg. Chim. Acta, 1995, vol. 234, nos. 1–2, p. 67.
Rasmussen, J.C., Toftlund, H., Nivorzhkin, A.N., et al., Inorg. Chim. Acta, 1996, vol. 251, nos. 1–2, p. 291.
Uraev, A.I., Vasil’chenko, I.S., Borodkin, G.S., et al., Izv. Akad. Nauk, Ser. Khim., 2005, vol. 54, no. 3, p. 623.
Kukushkin, Yu.N., Khodzhaev, O.F., Budanova, V.F., and Parpiev, N.A., Termoliz koordinatsionnykh soedinenii (Thermolysis of Coordination Compounds), Tashkent: Fan, 1986.
Kahn, O., Molecular Magnetism, New York: VCH Publishers, 1993.
Bleaney, B. and Bowers, K.D., Proc. R. Soc. London. A, 1952, vol. 214, no. 1119, p. 451.
Yamamoto, T., X-ray Spectrom., 2008, vol. 37, no. 6, p. 572.
Nagatani, H., Tanida, H., Watanabe, I., and Sagara, T., Anal. Sci., 2009, vol. 25, no. 4, p. 475.
Chen, L.X., Shaw, G.B., Liu, T., et al., Chem. Phys., 2004, vol. 299, nos. 2–3, p. 215.
Choy, J.-H., Yoon, J.-B., and Jung, H., J. Phys. Chem. B, 2002, vol. 106, no. 43, p. 11120.
Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N., et al., Russ. J. Coord. Chem., 2013, vol. 39, no. 10, p. 689.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.I. Uraev, L.D. Popov, S.I. Levchenkov, I.N. Shcherbakov, V.G. Vlasenko, K.Yu. Suponitskii, S.S. Beloborodov, D.A. Garnovskii, V.A. Kogan, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 9, pp. 515–522.
Rights and permissions
About this article
Cite this article
Uraev, A.I., Popov, L.D., Levchenkov, S.I. et al. Copper(II) and nickel(II) complexes with bis(azomethine)—a condensation product of 1-phenyl-3-methyl-4-formyl-5-mercaptopyrazole with 1,3-diaminopropan-2-ol. Russ J Coord Chem 40, 599–606 (2014). https://doi.org/10.1134/S1070328414090115
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328414090115