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Novel 1D Mn(II) complexes containing aromatic dicarboxylic acids

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Abstract

Three Mn(II) complexes of [MnL(Bipy)(H2O)] n (I), [Mn3(Phen)2(HL)2(L)2]n (II), and [Mn(Phen)2(HL)(OH)] (III), where L = 4,4′-(2-acetylpropane-1,3-diyl)dibenzoic acid, Bipy = 2,2′-bipyridine, and Phen = 1,10-phenanthroline, were hydrothermally synthesized and characterized by single crystal X-ray diffractions, infrared spectroscopy, thermogravimetric analyses, and magnetic analyses. Complexes I and II are one dimensional (1D) coordination polymers which can form the supramolecules with the help of the intermolecular hydrogen bond interactions. Finally, the landé factors are simulated by magentochemical analysis to be 2.15 and 1.80 for I and II with S = 5/2, respectively.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun, 130022, P.R. China

    D. Zhao, T. Shi, C. Chen, Z. Si & Q. Duan

  2. College of Sciences, Zhejiang A & F University, Lin’an, 311300, P.R. China

    L. Shi

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  1. D. Zhao
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  2. T. Shi
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  3. C. Chen
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  4. Z. Si
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  5. Q. Duan
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  6. L. Shi
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Correspondence to Z. Si.

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Zhao, D., Shi, T., Chen, C. et al. Novel 1D Mn(II) complexes containing aromatic dicarboxylic acids. Russ J Coord Chem 40, 224–231 (2014). https://doi.org/10.1134/S1070328414030117

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  • DOI: https://doi.org/10.1134/S1070328414030117

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