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Heterometallic cluster [CpMn(CO)2]2S2Ni(Dppe) containing the binuclear manganese disulfide complex as a ligand

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Abstract

A reaction of the disulfide complex [CpMn(CO)2]2S2 with the Ni(0) diphosphine acetylene complex, (Dppe)Ni(C2Ph2) (I), yielded the heterometallic complex [CpMn(CO)2]2S2Ni(Dppe) (II). An X-ray diffraction study revealed lateral coordination of the disulfide group to the Ni atom in complex II, which results in lengthening of both the S-S and Mn-S bonds against those in the starting complex. However, the Mn-S and Ni-S bonds are still much shorter than the sums of the covalent radii of the corresponding atoms.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. A. Pasynskii, I. V. Skabitskii & M. V. Karpacheva

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  1. A. A. Pasynskii
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  2. I. V. Skabitskii
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  3. M. V. Karpacheva
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Correspondence to A. A. Pasynskii.

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Original Russian Text © A.A. Pasynskii, I.V. Skabitskii, M.V. Karpacheva, 2013, published in Koordinatsionnaya Khimiya, 2013, Vol. 39, No. 3, pp. 131–135.

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Pasynskii, A.A., Skabitskii, I.V. & Karpacheva, M.V. Heterometallic cluster [CpMn(CO)2]2S2Ni(Dppe) containing the binuclear manganese disulfide complex as a ligand. Russ J Coord Chem 39, 229–233 (2013). https://doi.org/10.1134/S1070328413030068

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  • DOI: https://doi.org/10.1134/S1070328413030068

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