Skip to main content
Log in

Hydrothermal synthesis, crystal structural, and thermal properties of a 1D zinc coordination polymer based on benzoate and flexible bis(benzimidazole) ligands

Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

A new coordination polymer, [Zn(PhCOO)2(Bbbm)] n (I), where Bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TG and X-ray single-crystal diffraction. The complex crystallizes in the monoclinic system with space group P21/n, the unit cell parameters: a = 10.815(3), b = 20.516(6), c = 12.802(4) Å, β = 102.025(3)°, V = 2778.2(14) Å3, Z = 4. In this structure, the Zn2+ ion is in a distorted tetrahedral geometry, one-dimensional linear chain is constructed by Bbbm ligand with bis(monodentate) coordination mode.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Batten, S.R. and Robson, R., Angew. Chem., Int. Ed. Engl., 1998, vol. 37, p. 1460.

    Article  Google Scholar 

  2. Li, J.R., Kuppler, R.J., and Zhou, H.C., Chem. Soc. Rev., 2009, vol. 38, p. 1477.

    Article  CAS  Google Scholar 

  3. Cui, G.H., Liu, T.F., and Peng, X., J. Chem. Crystallogr., 2011, vol. 41, p. 322.

    Article  CAS  Google Scholar 

  4. Liu, T.F., Wu, W.F., Wan, C.Q., et al., J. Coord. Chem., 2011, vol. 64, p. 975.

    Article  CAS  Google Scholar 

  5. Liu, T.F., Zhang, M.X., Zhang, W.G., et al., Chin. J. Struct. Chem., 2011, vol. 30, p. 508.

    CAS  Google Scholar 

  6. Farha, O.K. and Hupp, J.T., Acc. Chem. Res., 2010, vol. 43, p. 1166.

    Article  CAS  Google Scholar 

  7. Li, J.R. and Zhou, H.C., Nature Chem., 2010, vol. 2, p. 893.

    Article  Google Scholar 

  8. Shi, X.J., Wang, X., Li, L.K., et al., Cryst. Growth Des., 2010, vol. 10, p. 2490.

    Article  CAS  Google Scholar 

  9. Robin, A.Y. and Fromm, K.M., Coord. Chem. Rev., 2006, vol. 250, p. 2127.

    Article  CAS  Google Scholar 

  10. Song, W.C., Li, J.R., Song, P.C., et al., Inorg. Chem., 2009, vol. 48, p. 3792.

    Article  CAS  Google Scholar 

  11. Liu, T.F., Lü, J., and Cao, R., CrystEngComm., 2010, vol. 12, p. 660.

    Article  CAS  Google Scholar 

  12. Gu, Z.G., Xu, Y.F., Zhou, X.H., et al., Cryst. Growth Des., 2008, vol. 8, p. 1306.

    Article  CAS  Google Scholar 

  13. Du, J.L., Hu, T.L., Zhang, S.M., et al., CrystEng-Comm., 2008, vol. 10, p. 1866.

    Article  CAS  Google Scholar 

  14. Cui, G.H., Li, J.R., Tian, J.L., et al., Cryst. Growth Des., 2005, vol. 5, p. 1775.

    Article  CAS  Google Scholar 

  15. Li, S.L., Lan, Y.Q., Qin, J.S., et al., Cryst. Growth Des., 2009, vol. 9, p. 4142.

    Article  CAS  Google Scholar 

  16. Li, Z.X., Chu, X., Cui, G.H., et al., CrystEngComm., 2011, vol. 13, p. 1984.

    Article  CAS  Google Scholar 

  17. Jiang, H., Liu, Y.Y., and Ma, J.F., Polyhedron, 2008, vol. 27, p. 2595.

    Article  CAS  Google Scholar 

  18. Wang, X.L., Zhang, J.X., Hou, L.L., et al., J. Chem. Crystallogr., 2011, vol. 10, p. 1579.

    Article  Google Scholar 

  19. She, J.B., Zhang, G.F., Dou, Y.L., et al., Acta Crystallogr., 2006, vol. 62, p. 402.

    Google Scholar 

  20. Sheldrick, G.M., SADABS, Program for Empirical Absorption Correction of Area Detector Data, Göttingen (Germany): Univ. of Göttingen, 1996.

    Google Scholar 

  21. Sheldrick, G.M., SHELXL-97, Program for X-Ray Crystal Structure Solution, Göttingen (Germany): Univ. of Göttingen, 1997

    Google Scholar 

  22. Sheldrick, G.M., SHELXL-97. Program for X-Ray Crystal Structure Refinement, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to G. H. Cui.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, C.J., Wang, F., Ruo, H.R. et al. Hydrothermal synthesis, crystal structural, and thermal properties of a 1D zinc coordination polymer based on benzoate and flexible bis(benzimidazole) ligands. Russ J Coord Chem 39, 222–224 (2013). https://doi.org/10.1134/S1070328413020127

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328413020127

Keywords

Navigation