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Reaction of [VO(OPr)3] with hexamethyldisylthiane in the presence of β-diketones

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Abstract

The reaction of [VO(OPr)3] (Pr is n-propyl) with hexamethyldisylthiane Me3SiSSiMe3 in the presence of β-diketones (acetylacetone (HAcac), hexafluoroacetylacetone (Hfac), and dipivaloylmethane (Dpm)), is studied. In all cases, vanadium(IV) and vanadium(III) β-diketonate complexes of different types are formed. New crystalline modification [V(Acac)3] is obtained in the reaction with HAcac. The mixedligand vanadium(III) complex of the composition [V2(Hfac)2(μ-OPr)]2 is formed with Hfac. In the presence of Dpm, the known vanadium(IV) complex [V2O2(Dpm)2(μ-OPr)2] is obtained in which two vanadyl groups VO2+ are linked by two bridging propoxy groups. The structures of all products are determined by X-ray diffraction analysis.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    M. N. Sokolov, A. V. Virovets, A. V. Rogachev, P. A. Abramov & V. P. Fedin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    M. N. Sokolov, P. A. Abramov & V. P. Fedin

Authors
  1. M. N. Sokolov
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  2. A. V. Virovets
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  3. A. V. Rogachev
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  4. P. A. Abramov
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  5. V. P. Fedin
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Corresponding author

Correspondence to M. N. Sokolov.

Additional information

Original Russian Text © M.N. Sokolov, A.V. Virovets, A.V. Rogachev, P.A. Abramov, V.P. Fedin, 2013, published in Koordinatsionnaya Khimiya, 2013, Vol. 39, No. 2, pp. 86–91.

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Sokolov, M.N., Virovets, A.V., Rogachev, A.V. et al. Reaction of [VO(OPr)3] with hexamethyldisylthiane in the presence of β-diketones. Russ J Coord Chem 39, 175–180 (2013). https://doi.org/10.1134/S1070328413020085

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  • DOI: https://doi.org/10.1134/S1070328413020085

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