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Synthesis and crystal structure of the porous metal-organic coordination polymer [Zn4(Ndc)4(Oxdz)2] · 2H2O

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Abstract

New metal-organic coordination polymer [Zn4(Ndc)4(Oxdz)2] · 2H2O (H2Ndc = 2,6-naphthalenedicarboxylic acid, Oxdz = 1,3,4-oxadiazole) was prepared by heating a solution of zinc nitrate, naphthalenedicarboxylic acid, and 4-aminotriazole in DMF. Of particular interest is the in situ transformation of 4-aminotriazole into 1,3,4-oxadiazole. The structure and the composition of the obtained compounds were established by X-ray diffraction, IR spectroscopy, and elemental analysis. The metal-organic framework is electrically neutral and forms a channel structure with the pore diameter of 9 Å.

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Correspondence to V. P. Fedin.

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Original Russian Text © S.B. Aliev, D.G. Samsonenko, V.P. Fedin, 2013, published in Koordinatsionnaya Khimiya, 2013, Vol. 39, No. 2, pp. 67–70.

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Aliev, S.B., Samsonenko, D.G. & Fedin, V.P. Synthesis and crystal structure of the porous metal-organic coordination polymer [Zn4(Ndc)4(Oxdz)2] · 2H2O. Russ J Coord Chem 39, 157–160 (2013). https://doi.org/10.1134/S1070328413020012

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  • DOI: https://doi.org/10.1134/S1070328413020012

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