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Synthesis, characterization, and crystal structure of bis[4-(3′-benzoyl)thiocarbamidophenyl]ether

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Abstract

The title compound, bis[4-(3′-benzoyl)thiocarbamidophenyl]ether, was synthesized by the reaction of benzoylisothiocyanate with 4,4′-diaminodiphenylether in aprotic solvent. The structure was determinated by means of elemental analysis and FT-IR, 1H-NMR, 13C-NMR and MS spectroscopic techniques. The crystal structure was characterized by X-ray syngle crystal analysis: orthorhombic, sp. gr. Pnna, Z = 4. In crystal packing, there are intramolecular hydrogen bond N-H⋯O generating S(6) motif, and intermolecular hydrogen bond N-H⋯S forming R 22 (8) ring.

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Authors and Affiliations

  1. Department of Chemistry, Science & Arts Faculty, Çanakkale Onsekiz Mart University, TR-17100, Çanakkale, Turkey

    F. Aydin & D. Aykaç

  2. Department of Computer Education and Instructional Technology, Faculty of Education, Giresun University, Giresun, Turkey

    N. Burcu Arslan

  3. Physics Department, Science & Art Faculty, Ondokuz Mayts University, TR-55139, Samsun, Turkey

    C. Kazak

Authors
  1. F. Aydin
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  2. D. Aykaç
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  3. N. Burcu Arslan
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  4. C. Kazak
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Correspondence to F. Aydin.

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Aydin, F., Aykaç, D., Burcu Arslan, N. et al. Synthesis, characterization, and crystal structure of bis[4-(3′-benzoyl)thiocarbamidophenyl]ether. Crystallogr. Rep. 59, 955–960 (2014). https://doi.org/10.1134/S1063774514070050

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  • DOI: https://doi.org/10.1134/S1063774514070050

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