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New organized systems based on amphiphilic oxyethylated calix[4]arene

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Abstract

The aggregation of amphiphilic oxyethylated calix[4]arene is studied in the absence and presence of polyethyleneimine. At low calixarene concentrations, large ensembles with a hydrodynamic diameter of about 100 nm are formed and coexist with small (smaller than 10 nm) aggregates, which are observed in the entire concentration range. It is established that calixarene-based systems catalyze the neutral hydrolysis of bis(chloromethyl)phosphinic acid p-nitrophenyl ester, with the catalytic effect being as high as two orders of magnitude in the presence of La(III) ions. The rate of hydrolysis of phosphonates depends on the composition of the supramolecular system. The maximum acceleration exceeds three orders of magnitude in comparison with alkaline hydrolysis of the substrates.

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References

  1. Yadava, P., Buethe, D., and Hughes, J., ACS Symp. Ser., 2006, vol. 14, no. 923, p. 198.

    Article  Google Scholar 

  2. Vriezema, D., Aragones, M., Elemans, J., et al., Chem. Rev., 2005, vol. 105, p. 1445.

    Article  CAS  Google Scholar 

  3. Dwars, T., Paetzold, E., and Oehme, G., Angew. Chem., Int. Ed. Engl., 2005, vol.44, p. 7174.

    Article  CAS  Google Scholar 

  4. Gutsche, C., Calixarenes, Cambridge: Royal Society of Chemistry, 1989.

    Google Scholar 

  5. Morohashi, N., Narumi, F., Iki, N., et al., Chem. Rev., 2006, vol.106, p. 5291.

    Article  CAS  Google Scholar 

  6. Gutsche, C., Calixarenes Revisited, Cambridge: Royal Society of Chemistry, 1998.

    Google Scholar 

  7. Steed, J.W. and Atwood, J.L., Supramolecular Chemistry, Chichester: Wiley, 2000.

    Google Scholar 

  8. Antipin, I., Zakharova, L., Solovieva, S., et al., RF Patent 2362761, 2009.

  9. Syakaev, V., Mustafina, A., Elistratova, Yu., et al., Supramol. Chem., 2008, vol.20, p. 453.

    Article  CAS  Google Scholar 

  10. Zakharova, L., Syakaev, V., Voronin, M., et al., J. Phys. Chem., 2009, vol.113, p. 6182.

    Article  CAS  Google Scholar 

  11. Mustafina, A., Zakharova, L., Elistratova, Ju., et al., J. Colloid Interface Sci., 2010, vol.346, p. 405.

    Article  CAS  Google Scholar 

  12. Zakharova, L., Kudryashova, Yu., Selivanova, N., et al., J. Membr. Sci., 2010, vol.364, p. 90.

    Article  CAS  Google Scholar 

  13. Ablakova, Yu., Valeeva, F., Ibragimova, A.M., et al., Kinet. Katal., 2011, vol.52, p. 56.

    Google Scholar 

  14. Toy, D.F. and Rattenbury, K.H., US Patent 2,922,810, 1960.

  15. Berezin, I.V., Martinek, K., and Yatsimirskii, A.K., Usp. Khim., 1973, vol.42, p. 1729.

    CAS  Google Scholar 

  16. Guinier, A., Theorie et technique de la cristallographie, Paris: Dunod, 1956.

    Google Scholar 

  17. Attwood, D., Adv. Colloid Interface Sci., 1995, vol.55, p. 271.

    Article  CAS  Google Scholar 

  18. Schneider, H.-J., Angew. Chem., Int. Ed. Engl., 2009, vol.48, p. 2.

    Google Scholar 

  19. Nishio, M., Hirota, M., and Umezawa, Y., The CH/π Interaction. Evidence, Nature, and Consequences, New York: Wiley-VCH, 1998.

    Google Scholar 

  20. Svergun, D.I. and Feigin, L.A., Rentgenovskoe i neitronnoe malouglovoe rasseyanie (Small-Angle X-Ray and Neutron Scattering), Moscow: Nauka, 1987.

    Google Scholar 

  21. Israelachvili, J.N., Mitchell, D.J., and Ninham, B.W., J. Chem. Soc., Faraday Trans., 1976, vol.72, p. 1525.

    Article  Google Scholar 

  22. Wu, C., Hou, Y., Deng, M., et al., Langmuir, 2010, vol.26, p. 7922.

    Article  CAS  Google Scholar 

  23. Mohanty, A., Patra, T., and Dey, J., J. Phys. Chem., 2007, vol.111, p. 7155.

    Article  CAS  Google Scholar 

  24. Zakharova, L., Ibragimova, A., Valeeva, F., et al., Langmuir, 2007, vol.23, p. 3214.

    Article  CAS  Google Scholar 

  25. Zakharova, L., Mirgorodskaya, A., Yackevich, E., et al., J. Chem. Eng. Data, 2010, vol.55, p. 5848.

    Article  CAS  Google Scholar 

  26. Zakharova, L., Ibragimova, A., Valeeva, F., et al., J. Phys. Chem., 2007, vol.111, p. 13839.

    CAS  Google Scholar 

  27. Zakharova, L.Ya., Valeeva, F.G., and Kudryavtseva, L.A., Zh. Obshch. Khim., 2002, vol.72, p. 1453.

    Google Scholar 

  28. Jencks, W.P., Catalysis in Chemistry and Enzimology, New York: McGraw-Hill, 1969.

    Google Scholar 

  29. Bakeeva, R., Kudryavtseva, L., Bel’skii, V., and Ivanov, B., Zh. Obshch. Khim., 1983, vol.53, p. 1058.

    CAS  Google Scholar 

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Original Russian Text © Yu.R. Kudryashova, F.G. Valeeva, L.Ya. Zakharova, S.E. Solovieva, I.S. Antipin, A.T. Gubaidullin, A.I. Konovalov, 2012, published in Kolloidnyi Zhurnal, 2012, vol. 74, No. 1, pp. 71–81.

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Kudryashova, Y.R., Valeeva, F.G., Zakharova, L.Y. et al. New organized systems based on amphiphilic oxyethylated calix[4]arene. Colloid J 74, 67–77 (2012). https://doi.org/10.1134/S1061933X12010085

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  • DOI: https://doi.org/10.1134/S1061933X12010085

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