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Electrochemical and electrocatalytic properties of meso-triphenylcorrole and its complexes with Mn(III), Co(III), Cu(III), and Zn(II)

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Abstract

The method of cyclic voltammetry (CV) was used to compare electrochemical and electrocatalytic properties of meso-triphenylcorrole [H3(ms-Ph)3Cor] and also its complexes with Mn(III), Co(III), Cu(III), and Zn(II) in 0.1M KOH. Metal-localized redox transitions are detected in the complexes of Mn (III → IV) and (III → II), Co (III → II), Cu (III → II). It is shown that the manganese complex features most effective catalytic properties in the reaction of molecular oxygen electroreduction.

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Correspondence to N. M. Berezina.

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Original Russian Text © M.I. Bazanov, N.M. Berezina, D.R. Karimov, D.B. Berezin, 2012, published in Elektrokhimiya, 2012, Vol. 48, No. 9, pp. 992–998.

The work was carried out in partnership with Research Institute of Macroheterocyclic Compounds and Research Institute of Thermodynamics and Kinetics of Chemical Processes of Ivanovo State University of Chemistry and Technology.

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Bazanov, M.I., Berezina, N.M., Karimov, D.R. et al. Electrochemical and electrocatalytic properties of meso-triphenylcorrole and its complexes with Mn(III), Co(III), Cu(III), and Zn(II). Russ J Electrochem 48, 905–910 (2012). https://doi.org/10.1134/S1023193512040039

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  • DOI: https://doi.org/10.1134/S1023193512040039

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