Abstract
Iodination, bromination, and thiocyanation reactions of the potassium salt K+[7,8-C2B9H12]− are investigated during diaphragm electrolysis. The B(9)-monosubstituted derivatives [9-X-7,8-C2B9H11]− (X = I, SCN) and disubstituted derivatives [9,11-X2-7,8-C2B9H10]− (X = Br, I) are obtained as alkylammonium salts. The composition and structure of these substances are confirmed by data from elemental analysis and IR and NMR (1H and 11B) spectroscopy.
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Original Russian Text © D.A. Rudakov, V.I. Potkin, I.V. Lantsova, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 7, pp. 873–877.
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Rudakov, D.A., Potkin, V.I. & Lantsova, I.V. Halogenation and thiocyanation of the univalent anion of dodecahydro-7,8-dicarba-nido-undecaborate in a diaphragm electrochemical cell. Russ J Electrochem 45, 813–817 (2009). https://doi.org/10.1134/S1023193509070179
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DOI: https://doi.org/10.1134/S1023193509070179