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Controlled synthesis of oligomeric poly(acrylic acid) and its behavior in aqueous solutions

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Abstract

The controlled synthesis of oligomeric poly(acrylic acid) via the pseudoliving radical reversible addition-fragmentation chain-transfer polymerization of acrylic acid in bulk is developed. It is shown that, at high concentrations of reversible addition-fragmentation chain-transfer agents, the polymerization of acrylic acid in bulk occurs via the pseudoliving mechanism, as evidenced by a linear increase in the numberaverage molecular mass of oligomers with conversion and a narrow molecular-mass distribution of the reaction products. The surfactant properties and behavior of the oligomers in aqueous solutions are studied.

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Authors and Affiliations

  1. Moscow University of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    E. A. Egorova, V. P. Zubov & I. V. Bakeeva

  2. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    E. V. Chernikova & E. A. Litmanovich

Authors
  1. E. A. Egorova
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  2. V. P. Zubov
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  3. I. V. Bakeeva
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  4. E. V. Chernikova
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  5. E. A. Litmanovich
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Corresponding author

Correspondence to E. V. Chernikova.

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Original Russian Text © E.A. Egorova, V.P. Zubov, I.V. Bakeeva, E.V. Chernikova, E.A. Litmanovich, 2013, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2013, Vol. 55, No. 9, pp. 1147–1153.

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Egorova, E.A., Zubov, V.P., Bakeeva, I.V. et al. Controlled synthesis of oligomeric poly(acrylic acid) and its behavior in aqueous solutions. Polym. Sci. Ser. A 55, 519–525 (2013). https://doi.org/10.1134/S0965545X13080026

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  • DOI: https://doi.org/10.1134/S0965545X13080026

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