Abstract
Variants of the single-step processing of unfractionated crude phenols by phenol—formaldehyde or oxidative oligomerization and/or complexation with organic substrates have been proposed. These treatments result in a significant increase in the inhibitory activity of the phenols and elimination of processing drawbacks of these substrates, such as unpleasant organoleptic properties and high solubility in water, and foremost make it possible to engage coal tar phenols back in petrochemical processes as polymerization inhibitors.
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References
V. V. Ershov, G. A. Nikiforov, and A. A. Volod’kin, Sterically Hindered Phenols (Khimiya, Moscow, 1972) [in Russian].
V. A. Roginskii, Phenolic Antioxidants: Reactivity and Efficiency (Nauka, Moscow, 1988) [in Russian].
A. N. Zav’yalov, Yu. M. Gol’dshmidt, Z. A. Zav’yalova, and L. V. Kasilova, Wood Tar and Other Inhibitors of Chain Processes (VNIPIEIlesprom, Moscow, 1978) [in Russian].
A. D. Berents, A. V. Vol’-Epshtein, T. N. Mukhina, and G. L. Avrekh, Processing of Liquid Pyrolysis Products (Khimiya, Moscow, 1985) [in Russian].
S. V. Gusarov, A. M. Danilov, A. S. Kryukov, et al., Neftepererab. Neftekhim., No. 3, 20 (1993).
A. Knop and W. Scheib, Chemistry and Application of Phenolic Resins (Springer, Heidelberg, 1979).
A. H. Haines, Methods for Oxidation of Organic Compounds: Alkanes, Alkenes, Alkynes, and Arenes (Academic, London, 1986).
G. F. Zakis, Synthesis of Model Lignin Compounds (Zinatne, Riga, 1980) [in Russian].
G. A. Kalabin, L. V. Kanitskaya, and D. F. Kushnarev, Quantitative NMR Spectroscopy of Natural Organic Raw Materials and Their Processing Products (Khimiya, Moscow, 2000) [in Russian].
A. F. Gogotov, A. A. Zav’yalova, A. N. Zakazov, et al., Coke Chem., 50, 37 (2007).
A. I. Kamneva and V. V. Platonov, Theoretical Principles of Chemical Technology of Fossil Fuels (Khimiya, Moscow, 1990) [in Russian].
A. A. Levchuk, Extended Abstract of Candidate’s Dissertation in Engineering (Tomsk, 2010).
R. E. Karll and E. J. Piasek, RU Patent No. 3737465 (1973).
M. B. Manek, Ch. H. Chen, R. G. Presenti, and H. Diaz-Arau'zo, US Patent No. 5985940 (1999).
G. D. Kharlampovich and Yu. V. Churkin, Phenols (Khimiya, Moscow, 1974).
A. F. Gogotov, A. V. Ivanova, S. V. Gusarov, and V. K. Stankevich, RU Patent No. 2265005, Byull. Izobret., No. 33 (2005).
F. Lartigue-Peyrou, RU Patent No. 2154048, Byull. Izobret., No. 22, 394 (2000).
O. I. Baranov, A. F. Gogotov, A. A. Levchuk, et al., RU Appl. No. 2009108233/04, Byull. Izobret., No. 26, 179 (2010).
I. I. Batura, I. Yu. Chukicheva, A. F. Gogotov, et al., RU Patent No. 2375342, Byull. Izobret., No. 34 (2009).
I. I. Batura, I. Yu. Chukicheva, A. F. Gogotov, et al., RU Patent No. 2387631, Byull. Izobret., No. 12 (2010).
A. F. Gogotov, Do Chiem Tai, L. V. Kanitskaya, and V. K. Stankevich, Russ, J. Appl. Chem. 86, 1832 (2013).
A. F. Gogotov, RU Patent No. 2500660, Byull. Izobret., No. 34 (2013).
E. Breitmaier, Structure Elucidation by NMR in Organic Chemistry: A Practical Guide (Wiley, Chichester, 2002), 3rd Ed.
V. K. Turchaninov, N. N. Chipanina, Z. V. Stepanova, et al., Russ, J. Gen. Chem. 73, 440 (2003).
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Original Russian Text © A.F. Gogotov, A.A. Levchuk, Do Chiem Tai, L.V. Kanitskaya, V.K. Stankevich, 2015, published in Neftekhimiya, 2015, Vol. 55, No. 5, pp. 383–390.
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Gogotov, A.F., Levchuk, A.A., Tai, D.C. et al. Coal tar phenols as a promising intermediate for producing high-performance polymerization inhibitors in petrochemical industry. Pet. Chem. 55, 530–536 (2015). https://doi.org/10.1134/S096554411507004X
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DOI: https://doi.org/10.1134/S096554411507004X