Abstract
The nanofiltration of the water-ethanol mixture of different compositions at three pressure drops through a nanoporous membrane based on poly(1-trimethylsilyl-1-propyne) has been experimentally and theoretically studied. A mathematical model of the onset of flow has been proposed, and the percolation threshold depending on the physicochemical and geometrical characteristics of the membrane system has been found. The model suggests gradual membrane pore opening with an increase in pressure and alcohol concentration in the mixture and can take account of the distribution of alcohol molecules over the cross section of the membrane pores. The theoretical results agree well with the experimental data.
References
A. V. Volkov, G. A. Korneeva, and G. F. Tereshchenko, Usp. Khim. 77, 1053 (2008).
A. V. Volkov, V. V. Volkov, and V. S. Khotimskii, Polym. Sci., Ser. A 51, 1367 (2009).
A. V. Volkov, D. F. Stamatialis, V. S. Khotimsky, et al., J. Membr. Sci. 281, 351 (2006).
S. E. Volkov, M. B. Tsarkov, G. N. Gokzhaev, et al., Petr. Chem. 52, 598 (2012).
A. Volkov, A. Yushkin, A. Grekhov, et al., J. Membr. Sci. 440, 98 (2013).
S. Tanimura, R. Yamaguchi, S. I. Nakao, and S. Kimura, J. Chem. Eng. Jpn. 25, 580 (1992).
A. Grekhov, A. Belogorlov, A. Yushkin, and A. Volkov, J. Membr. Sci. 390/391, 160 (2012).
J. Geens, K. Peeters, B. van der Bruggen, and C. Vandecasteele, J. Membr. Sci. 255, 255 (2005).
S. Darvishmanesh, J. Degrève, and B. van der Bruggen, Chem. Eng. Sci. 64, 3914 (2009).
V. I. Ivanov, Vestn. Nizhegorodsk. Univ.: Mekh. Zhidk. Gaza, No. 4 (2), 438 (2011).
A. N. Filippov V. I. Ivanov, A. V. Volkov, et al., in Proceedings of International Conference on Ion Transport in Organic and Inorganic Membranes (Krasnodar-Tuapse, 2012), p. 71.
A. N. Filippov, V. I. Ivanov, Yu. G. Bogdanova, et al., in Proceedings of VI All-Russia Conference on Physicochemical Processes in Condensed Media and Interfaces (Voronezh, 2012) [in Russian], p. 476.
A. N. Filippov and V. I. Ivanov, in Proceedings of IV International Conference on Colloid Chemistry and Physicochemical Mechanics: Book of Abstracts (Moscow, 2013), p. 128.
V. S. Khotimsky, M. V. Tchirkova, E. G. Litvinova, et al., J. Polym. Sci., Part A: Polym. Chem. 41, 2133 (2003).
S. Tsarkov, V. Khotimskiy, P. M. Budd, et al., J. Membr. Sci. 423/424, 65 (2012).
S. E. Tsarkov, A. O. Malakhov, E. G. Litvinova, and A. V. Volkov, Pet. Chem. 53, 537 (2013).
A. Yushkin, A. Grekhov, S. Matson, et al., React. Funct. Polym. 86, 269 (2015).
A. Adamson, The Physical Chemistry of Surfaces (Wiley, New York, 1976).
J. Vojtechovska and L. Kvitek, Acta Univ. Palack. Olomuc. Fac. Rerum Nat., Chem. 44, 25 (2005).
D. Hofman, M. Heuchet, Yu. Yampolskii, et al., Macromolecules 35, 2129 (2002).
E. D. Shchukin, A. V. Pertsov, and E. A. Amelina, Colloid Chemistry (Vysshaya Shkola, Moscow, 2007) [in Russian].
Derjaguin, B.V., The Theory of Stability of Colloids and Thin Films (Nauka, Moscow, 1986) [in Russian]; Derjaguin, B.V., Churaev, N.V., and Muller, V.M., Surface Forces (Consultants Bureau, New York,:1987).
G. A. Martynov, V. M. Starov, and N. V. Churaev, Kolloidn. Zh., No. 4, 657 (1980).
E. A. Moelwyn-Hughes, Physical Chemistry (Pergamon, Oxford, 1961), 2nd Ed.
A. B. Gil’man, V. V. Volkov, A. I. Drachev, and Ya. A. Selinskaya, High Energy Chem. 34, 260 (2000).
P.-G. de Gennes, Usp. Fiz. Nauk 151, 619 (1987).
V. P. Shantarovich, I. B. Kevdina, Yu. P. Yampolskii, and A. Yu. Alentiev, Macromolecules 33, 7453 (2000).
S. M. Matson, K. Rätzke, M. Q. Shaikh, et al., Polym. Sci., Ser. A 54, 671 (2012).
E. Ruckenstein and G. O. Berim, Adv. Colloid Interface Sci. 157, 1 (2010).
V. M. Starov, M. G. Velarde, and C. J. Radke, Wetting and Spreading Dynamics, vol. 138 of Surfactant Science Series (CRC, Boca Raton, 2007).
V. I. Roldugin, Physical Chemistry of Surfaces (Intellekt, Dolgoprudnyi, 2008) [in Russian].
Yu. G. Bogdanova and V. D. Dolzhikova, Butlerovsk.Soobshch. 35(8), 81 (2013).
M. A. Biot, J. Appl. Phys. 33, 1482 (1962).
A. A. Kovtun, Uchen. Zap. Petersburgsk. Gos. Univ., Vopr. Geofiz. 44(444), 3 (2011).
V. A. Rabinovich and Z. Ya. Khavin, Concise Handbook of Chemistry (Khimiya, Leningrad, 1978) [in Russian].
A. N. Filippov, R. Kh. Iksanov, and A. V. Volkov, Petr. Chem. 51, 536 (2011).
G. McHale, M. I. Newton, and N. J. Shirtcliffe, Soft Matter 6, 714 (2010).
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Original Russian Text © A.N. Filippov, V.I. Ivanov, A.A. Yushkin, V.V. Volkov, Yu.G. Bogdanova, V.D. Dolzhikova, 2015, published in Membrany i Membrannye Tekhnologii, 2015, Vol. 5, No. 2, pp. 103–119.
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Filippov, A.N., Ivanov, V.I., Yushkin, A.A. et al. Simulation of the onset of flow through a PTMSP-based polymer membrane during nanofiltration of water-methanol mixture. Pet. Chem. 55, 347–362 (2015). https://doi.org/10.1134/S0965544115050059
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DOI: https://doi.org/10.1134/S0965544115050059