, Volume 52, Issue 3, pp 179-185
Date: 15 May 2012

Catalytic aminomethylation of alkenes in a dimethylformamide medium

Abstract

The hydroaminomethylation of alkenes with dimethylamine catalyzed by rhodium and ruthenium complexes in a dimethylformamide medium under synthesis-gas pressures of 2 MPa has been studied. It has been shown that the combined use of these metals leads to a significant increase in the rate of formation of amines and selectivity for n-alkyldimethylamine. It has been found that the reaction can proceed with dimethylformamide used as an aminating agent without the addition of dimethylamine.

Original Russian Text © E.A. Karakhanov, E.A. Runova, Yu.S. Kardasheva, D.V. Losev, A.L. Maksimov, M.V. Terenina, 2012, published in Neftekhimiya, 2012, Vol. 52, No. 3, pp. 204–210.