Abstract
This study focuses on Jurassic shallow intrusions and subvolcanic bodies from around Trudolyubovka village in the southwestern Crimea. All the rocks are similar in mineral composition and have similar geochemical features and occur in close spatial and geological association. This allows us to assign the intrusions to a single magmatic series and interpret them as differentiation products of a single parental melt. The investigation of melt inclusions in olivine from the most magnesian sample showed that the composition of igneous melts ranged from basalt to basaltic andesite of a moderately potassic subalkaline affinity. Compared with N-MORB, they are enriched in LILE, but have similar HFSE and REE contents. The early magmatic melts crystallized at temperatures ranging from 1240 to 1125°C, pressures of 6–8 kbar, and an oxygen fugacity of ΔQFM = +0.6; and later melts crystallized at 1090–940°C, ~1.5 kbar, and oxygen fugacity increasing from ΔQFM + 0.9 to ΔQFM + 2.3. The minimum pressure of groundmass crystallization was estimated as 40–60 bar. The primitive melts were formed in a mature island arc or an active continental margin setting by ~13% melting of a DMM-like source. The melting occurred at spinel-facies depths under the influence of a slab-derived fluid at a temperature 25°C below the dry peridotite solidus.
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Almeev, R.R., Holtz, F., Koepke, J., et al., The effect of H2O on olivine crystallization in MORB: experimental calibration at 200 MPa, Am. Mineral., 2007, vol. 92, no. 4, pp. 670–674.
Arai, S, Characterization of spinel peridotites by olivine–spinel compositional relationships: review and interpretation, Chem. Geol., 1994, vol. 113, no. 3, pp. 191–204.
Ariskin, A.A., Frenkel, M.Y., Barmina, G.S., and Nielsen, R.L., COMAGMAT: a FORTRAN program to model magma differentiation processes, Comput. Geosci., 1993, vol. 19, no. 8, pp. 1155–1170.
Bagdasaryan, G.P. and Lebedinskii, V.I, New data on the absolute age of magmatic rocks of Gorny Crimea, Dokl. Akad. Nauk SSSR, 1967, vol. 173, no. 1, pp. 149–152.
Ballhaus, C., Berry, R.F., and Green, D.H, High pressure experimental calibration of the olivine–orthopyroxene–spinel oxygen geobarometer: implications for the oxidation state of the upper mantle, Contrib. Mineral. Petrol., 1991, vol. 107, no. 1, pp. 27–40.
Borisov, A.A. and Shapkin, A.I., A new empirical equation relating Fe3+ /Fe2+ in magmas to their composition, oxygen fugacity, and temperature, Geochem. Int., 1990, vol. 27, no. 1, pp. 111–116.
Bucholz, C.E., Gaetani, G.A., Behn, M.D., et al., Postentrapment modification of volatiles and oxygen fugacity in olivine-hosted melt inclusions, Earth Planet. Sci. Lett., 2013, vol. 374, pp. 145–155.
Danyushevsky, L.V. and Plechov, P., Petrolog3: integrated software for modeling crystallization processes, Geochem. Geophys. Geosyst., 2011, vol. 12, Q07021, doi 10.1029/2011GC003516
Danyushevsky, L.V., Della-Pasqua, F.N., and Sokolov, S., Re-equilibration of melt inclusions trapped by magnesian olivine phenocrysts from subduction-related magmas: petrological implications, Contrib. Mineral. Petrol., 2000, vol. 138, no. 1, pp. 68–83.
Danyushevsky, L.V., Sokolov, S., and Falloon, T.J, Melt inclusions in olivine phenocrysts: using diffusive re-equilibration to determine the cooling history of a crystal, with implications for the origin of olivine-phyric volcanic rocks, J. Petrol., 2002, vol. 43, no. 9, pp. 1651–1671.
Dovgal’, Yu.M., Radzivil V.Ya., Tokovenko, V.S., et al., Vulkany Karadag (Volkanoes of Karadag), Kiev: Naukova dumka, 1991.
Fedorchuk A.V. and Glukhov, A.M, Petrographic types of subvolcanic bodies of the Bodrak River valley and their age, in Region. Geol. Nekot. Reg. SSSR, 1980, no. 4, pp. 39–45.
Feig, S., Koepke, J., and Snow, J, Effect of water on tholeiitic basalt phase equilibria: an experimental study under oxidizing conditions, Contrib. Mineral. Petrol., 2006, vol. 152, no. 5, pp. 611–638.
Ford, C.E., Russell, D.G., Craven, J.A., and Fisk, M.R, Olivine–liquid equilibria: temperature,pressure and composition dependence of the crystal/liquid cation partition coefficients for Mg,Fe2+,Ca and Mn, J. Petrol., 1983, vol. 24, no. 3, pp. 256–266.
Gavrilenko, M., Herzberg, C., Vidito, C., et al., A calciumin-olivine geohygrometer and its application to subduction zone magmatism, J. Petrol., 2016, vol. 57, no. 9, pp. 1811–1832.
Genç, S.C. and Tüysüz, O, Tectonic setting of the Jurassic bimodal magmatism in the Sakarya Zone (Central and Western Pontides), Northern Turkey: a geochemical and isotopic approach, Lithos, 2010, vol. 118, no. 1, pp. 95–111.
Gill, J., Orogenic Andesites and Plate Tectonics, Berlin: Springer-Verlag, 1981.
Ginibre, C., Kronz, A., and Wörner, G., High-resolution quantitative imaging of plagioclase composition using accumulated backscattered electron images: new constraints on oscillatory zoning, Contrib. Mineral. Petrol., 2002, vol. 142, no. 4, pp. 436–448.
Gnidets, V.P., Grigorchuk, K.G., Zakharchuk, S.M., et al., Neftegazoperspectivnyi ob’ekty Ukrainy. Geologiya nichnego mela Prichernomorsko–Krymskoi neftegazonosnoi oblasti (geologostrukturnyi usloviya, sediment-litogenezis, porody kollektory, perspektivy neftegazonosnosti) (Oil and Gas Prospects of Ukraine. Geology of the Lower Cretaceous of the Black Sea–Crymean Petroleum Area: Geological-Structural Conditions, Sedimentation, Lithogenesis, Reservoir Rocks, and Petroleum Prospects), Kiev: EKMO, 2010.
Ionov, D.A., Benard, A., and Plechov, P.Y, Melt evolution in subarc mantle: evidence from heating experiments on spinel- hosted melt inclusions in peridotite xenoliths from the andesitic Avacha volcano (Kamchatka, Russia), Contrib. Mineral. Petrol., 2011, vol. 162, no. 6, pp. 1159–1174.
Jaques, A.L. and Green, D.H, Anhydrous melting of peridotite at 0–15 kb pressure and the genesis of tholeiitic basalts, Contrib. Mineral. Petrol., 1980, vol. 73, no. 3, pp. 287–310.
Jarosewich, E., Nelen, J.A., and Norberg, J.A, Reference samples for electron microprobe analysis, Geostand. Newslett., 1980, vol. 4, no. 1, pp. 43–47.
Jochum, K.P. and Dingwell, D.B., Rocholl, A., et al., The preparation and preliminary characterisation of eight geological MPI-DING reference glasses for in-situ microanalysis, Geostand. Newslett., 2000, vol. 24, no. 1, pp. 87–133.
Jochum, K.P., Willbold, M., Raczek, I., et al., Chemical characterisation of the USGS reference glasses GSA-1G,GSC-1G,GSD-1G,GSE-1G,BCR-2G,BHVO-2G and BIR-1G using EPMA,ID-TIMS,ID-ICP-MS and LAICP-MS, Geostand. Geoanal. Res., 2005, vol. 29, no. 3, pp. 285–302.
Kopaevich, L.F. and Khotylev, A.O. The stratigraphic setting of Cretaceous volcanic rocks in Crimea and in the North Caucasus, Mosc. Univ. Geol. Bull., 2014, vol. 69, no. 6, pp. 433–444.
Latyshev, A.V. and Panov, D.I, Jurassic magmatic bodies of Mountainous Crimea in the Bodrak River catchment (Southwestern Crimea), Mosc. Univ. Geol. Bull., 2008, vol. 63, no. 2, pp. 70–78.
Le Bas, M.J., Le Maitre, R.W., Streckeisen, A., and Zanettin, B., A chemical classification of volcanic-rocks based on the total alkali silica diagram, J. Petrol., 1986, vol. 27, no. 3, pp. 745–750.
Lebedinskii, V.I. and Makarov, N.N., Vulkanizm Gornogo Kryma (Volcanism of Mountain Crimea), Kiev: AN USSR, 1962.
Lindsley, D.H, Pyroxene thermometry, Am. Mineral., 1983, vol. 68, nos. 5–6, pp. 477–493.
Loucks, R.R., A precise olivine–augite Mg–Fe-exchange geothermometer, Contrib. Mineral. Petrol., 1996, vol. 125, nos. 2–3, pp. 140–150.
Luchitskii, V.I., Petrography of Crimea, in Regional’naya petrografiya (Regional Petrography), Moscow: AN SSSR,1939, vol. 8.
Mallmann, G. and O’Neill, H.S.C, Calibration of an empirical thermometer and oxybarometer based on the partitioning of Sc,Y and V between olivine and silicate melt, J. Petrol., 2013, vol. 54, no. 5, pp. 933–949.
Meijers, M.J.M., Vrouwe, B., van Hinsbergen, D.J.J., et al., Jurassic arc volcanism on Crimea (Ukraine): implications for the paleo-subduction zone configuration of the Black Sea region, Lithos, 2010, vol. 119, no. 3, pp. 412–426.
Morimoto, N, Nomenclature of pyroxenes, Mineral. Petrol., 1988, vol. 39, no. 1, pp. 55–76.
Morozova E.B., Sergeev S.A., and Sufiev, A.A., U–Pb zircon (SHRIMP) ages of the Dzhidair Intrusin as reference object for Crimean geology (Crimean test site of St. Petersburg State University), Vestn. St. Peterb. Gos. Univ., Ser. 7, 2012, no. 4, pp. 25–33.
Mudrenko, S.V., Pechnikov, V.A., and Samsonenko, V.L, Hypabyssal and subvolcanic rocks of the Bodrak–Salgir zone (piedmont Crimea), Regional. Geol. Nekot. Raion. SSSR, 1983, no. 6, pp. 18–23.
Muratov, M.V., Kratkii ocherk geologicheskogo stroeniya krymskogo poluostrova (Brief Essay on the Geological Structure of the Crimean Peninsula), Moscow: GONTI, 1960.
Newman, S. and Lowerstern, J.B, VolatileCalc: a silicate melt–H2O–CO2 solution model written in Visual Basic for Excel, Comput. Geosci., 2002, vol. 28, no. 5, pp. 597–604.
Nikishin, A.M., Khotylev, A.O., Bychkov, A.Yu. et al., Cretaceous volcanic belts and the evolution of the Black Sea Basin, Mosc. Univ. Geol. Bull., 2013, vol. 68, no. 2, pp. 141–154.
Nikitin, M.Yu. and Bolotnov, S.N., Geologicheskoe stroenie Krymskogo uchebnogo poligona MGU. Chast’ 2 (Geological Structure of the Krymean Test Site of the Moscow State University Part 2), Moscow: MGU, 2007.
Nikitina, M.I., Pol’skikh, G.M., and Suslov, A.V, Some features of minor intrusions in the Bodrak river basin (Bakhchisarai area, Crymea), Izv. Vyssh. Ucheb. Zaved. Geol. Razvedka, 1979, no. 6, pp. 39–43.
Nimis, P., A clinopyroxene geobarometer for basaltic systems based on crystal structure modeling, Contrib. Mineral. Petrol., 1995, vol. 121, no. 2, pp. 115–125.
Okay, A.I. and Nikishin, A.M, Tectonic evolution of the southern margin of Laurasia in the Black Sea region, Int. Geol. Rev., 2015, vol. 57, nos. 5–8, pp. 1051–1076.
Panov, D.I. and Stepanov, A.G, Lower Jurassic volcanogeic horizon on the Bodrak–Al’ma watershed (Mountainous Crimea) and its analogues in the Mountainous Crimea and Greater Caucasus, Vestn. Mosk. Univ., Geol., Ser. 4, 2002, no. 1, pp. 14–21.
Pearce, J.A., Role of the subcontinental lithosphere in magma genesis at active continental margins, in Continental Basalts and Mantle Xenoliths, Hawkesworth, C.J. and Norry, M.J., Eds., Cheshire: Shiva, 1983, pp. 230–249.
Plechov, P.Yu. and Popov D.V, The character of volcanic activity in southwestern Crimea during the Late Albian, Mosc. Univ. Geol. Bull., 2014, vol. 69, no. 5, pp. 299–307.
Plechov, P., Blundy, J., Nekrylov, N., et al., Petrology and volatile content of magmas erupted from Tolbachik volcano,Kamchatka,2012–13, J. Volcanol. Geotherm. Res., 2015, vol. 307, pp. 182–199.
Popov D.V., Nekrylov N.A., Plechov P.Yu. The petrology of the Upper Albian tuffites from the Bakhchysarai district, southwestern Crimea, Mosc. Univ. Geol. Bull., 2016, vol. 71, no. 2, pp. 194–204.
Portnyagin, M., Hoernle, K., Plechov, P., et al., Constraints on mantle melting and composition and nature of slab components in volcanic arcs from volatiles (H2O,S,Cl,F) and trace elements in melt inclusions from the Kamchatka arc, Earth Planet. Sci. Lett., 2007, vol. 255, no. 1, pp. 53–69.
Portnyagin, M., Almeev, R., Matveev, S., and Holtz, F, Experimental evidence for rapid water exchange between melt inclusions in olivine and host magma, Earth Planet. Sci. Lett, 2008, vol. 272, no. 3, pp. 541–552.
Promyslova, M.Yu., Demina, L.I., Bychkov, A.Yu., et al., Ophiolitic association of Cape Fiolent area, Southwestern Crimea, Geotectonics, 2016, vol. 50, no. 1, pp. 21–34.
Sen, C, Jurassic volcanism in the Eastern Pontides: is it rift related or subduction related?, Turk. J. Earth Sci., 2007, vol. 16, no. 4, pp. 523–539.
Shishkina, T.A., Botcharnikov, R.E., Holtz, F., et al., Solubility of H2O- and CO2-bearing fluids in tholeiitic basalts at pressures up to 500 MPa, Chem. Geol., 2010, vol. 277, no. 1, pp. 115–125.
Shnyukov E.F., Shcherbakov, I.B., Shnyukova, E.E., Paleoostrovnaya duga severa Chernogo morya (Paleoisland Arc of the Northern Black Sea), Kiev: NANU, 1997.
Simkin, T. and Smith, J.V., Minor-element distribution in olivine, J. Geol., 1970, pp. 304–325.
Sobolev, A.V. and Danyushevsky, L.V, Petrology and geochemistry of boninites from the north termination of the Tonga trench: constraints on the generation conditions of primary high-Ca boninite magmas, J. Petrol., 1994, vol. 35, no. 5, pp. 1183–1211.
Sobolev, A.V. and Slutskii, A.B, Composition and conditions of crystallization of the parental melt of the Siberian meymechites and relation with a general problem of ultrabasic magmas, Geol. Geofiz., 1984, no. 12, pp. 97–110.
Sobolev, A.V., Asafov, E.V., Gurenko, A.A., et al., Komatiites reveal a hydrous Archaean deep-mantle reservoir, Nature, 2016, vol. 531, no. 7596, pp. 628–632.
Solov’ev, A.V. and Rogov, M.A, First fission-track dating of zircons from Mesozoic complexes of the Crimea, Stratigraphy. Geol. Correlation, 2010, vol. 18, no. 3, pp. 298–306.
Spiridonov, E.M., Korotaeva, N.N., and Ladygin, V.M., Cr-spinel, Ti-magnetite, and ilmenite from island-arc volcanic rocks of Mountainous Crimea, Vestn. Mosk. Univ., Geol. Ser. 4, 1989, no. 6, pp. 37–55.
Spiridonov, E.M., Fedorov, T.O., and Ryakhovskii, V.M, Magmatic complexes of Mountainous Crimea: Paper 1, Byull. Mosk. O-va Ispyt. Prir., Otd. Geol., 1990a, vol. 65, no. 4, pp. 119–134.
Spiridonov, E.M., Fedorov, T.O., Ryakhovskii, V.M, Magmatic complexes of Mountainous Crimea: Paper 2, Byull. Mosk. O-va Ispyt. Prir., Otd. Geol., 1990b, vol. 65, no. 4, pp. 102–112.
Streck, M.J., Dungan, M.A., Bussy, F., and Malavassi, E, Mineral inventory of continuously erupting basaltic andesites at Arenal Volcano, Costa Rica: implications for interpreting monotonous, crystal-rich, mafic arc stratigraphies, J. Volcanol. Geotherm. Res., 2005, vol. 140, no. 1, pp. 133–155.
Sun, S.S. and McDonough, W.F, Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes, Geol. Soc. Spec. Publ., 1989, vol. 42, no. 1, pp. 313–345.
Sysolin A.I. and Pravikova N.V, Subvolcanic bodies of the Bodrak Complex in southwestern Crimea: structure, composition, and formation conditions, Mosk. Univ Geol. Bull., 2008, vol. 63, no. 2, pp. 79–85.
Wells, P.R.A, Pyroxene thermometry in simple and complex systems, Contrib. Mineral. Petrol., 1977, vol. 62, no. 2, pp. 129–139.
Workman, R.K. and Hart, S.R, Major and trace element composition of the depleted MORB mantle (DMM), Earth Planet. Sci. Lett., 2005, vol. 231, no. 1, pp. 53–72.
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Original Russian Text © D.V. Popov, N. Nekrylov, P.Yu. Plechov, V.D. Shcherbakov, M.V. Portnyagin, M.S. Serova, 2017, published in Petrologiya, 2017, Vol. 25, No. 3, pp. 265–298.
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Popov, D.V., Nekrylov, N., Plechov, P.Y. et al. Composition and conditions of formation of the parental melts of Jurassic dolerites of southwestern Crimea: Evidence from melt inclusions in olivine phenocrysts. Petrology 25, 272–303 (2017). https://doi.org/10.1134/S0869591117030031
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DOI: https://doi.org/10.1134/S0869591117030031