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Structure and properties of (1–x)LiPO3−x SiO2 and 50Li2O−(50–x)P2O5−x SiO2 glass-forming systems

  • Structure of Matter and Quantum Chemistry
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Abstract

The dependence of the structure and properties of two series of glasses (100–x)LiPO3−x SiO2, x = 0–20 (series I) and 50Li2O−(50–x)P2O5−x SiO2, x = 0–10 (series II) were studied. The amorphous state of the composites was confirmed by XRD. In series II, a mixed glass-forming effect was revealed with a nonmonotonic increase of the glass transition temperature and electric conductivity. The structural features of the glasses were studied by Raman and IR spectroscopy. In the Raman spectra, vibrations of SiO4 groups with three and four oxygen bridging atoms were found; in the IR spectra, the intensities of the bands of the metaphosphate units decreased, while those of the P–O–Si bonds and pyrophosphate groups increased; in system II, the ion conductivity increased with x at room temperature by more than an order of magnitude and reached its maximum of 3.6 × 10–8 S/cm at x = 5.

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References

  1. S. J. Lee, H. K. Baik, and S. M. Lee, Electrochem. Commun. 5, 32 (2003).

    Article  CAS  Google Scholar 

  2. S. D. Jones and J. R. Akridge, Solid State Ionics 69, 357 (1994).

    Article  CAS  Google Scholar 

  3. J. Saienga and S. W. Martin, J. Non-Cryst. Solids 354, 1475 (2008).

    Article  CAS  Google Scholar 

  4. B. Raguenet, G. Tricot, G. Silly, et al., Solid State Ionics 208, 25 (2012).

    Article  CAS  Google Scholar 

  5. B. Wang, B. S. Kwak, B. C. Sales, and J. B. Bates, J. Non-Cryst. Solids 183, 297 (1995).

    Article  CAS  Google Scholar 

  6. K. I. Cho, S. H. Lee, D. W. Shin, et al., Electroch. Acta 52, 1576 (2006).

    Article  CAS  Google Scholar 

  7. J. P. Malugani and G. Robert, Mater. Res. Bull. 14, 1075 (1979).

    Article  CAS  Google Scholar 

  8. R. Prasada Rao, T. D. Tho, and S. Adams, J. Power Sources 189, 385 (2009).

    Article  CAS  Google Scholar 

  9. T. Tsuchiya and T. Moriya, J. Non-Cryst. Solids 38–39, 323 (1980).

    Article  Google Scholar 

  10. R. Christensen, J. Byer, G. Olson, and S. W. Martin, J. Non-Cryst. Solids 358, 583 (2012).

    Article  CAS  Google Scholar 

  11. M. Tatsumisago, K. Yoneoa, N. Machida, and T. Minami, J. Non-Cryst. Solids 95–96, 857 (1987).

    Article  Google Scholar 

  12. E. A. Hayri and M. Greenblatt, J. Non-Cryst. Solids 94, 387 (1987).

    Article  CAS  Google Scholar 

  13. E. Metwalli, R. K. Brow, and F. S. Stover, J. Am. Ceram. Soc. 84, 1025 (2001).

  14. G. le Saout, P. Simon, F. Fayon, et al., J. Raman Spectrosc. 33, 740 (2002).

    Article  CAS  Google Scholar 

  15. J. J. Hudgens, R. K. Brow, D. R. Tallant, et al., J. Non-Cryst. Solids 223, 21 (1998).

    Article  CAS  Google Scholar 

  16. D. Toloman, A. R. Biris, D. Maniu, et al., Particulate Sci. Technol. 28, 226 (2010).

    Article  CAS  Google Scholar 

  17. P. G. Galliano, J. M. Porto Lopez, E. L. Varetti, et al., Mater. Res. Bull. 29, 1297 (1994).

    Article  CAS  Google Scholar 

  18. S. V. Pershina, A. A. Raskovalov, B. D. Antonov, et al., J. Non-Cryst. Solids 430, 64 (2015).

    Article  CAS  Google Scholar 

  19. P. P. Tsai and M. Greenblatt, J. Non-Cryst. Solids 103, 101 (1988).

    Article  CAS  Google Scholar 

  20. E. A. Hayri, M. Greenblatt, M. T. Tsai, et al., Solid State Ionics 37, 233 (1990).

    Article  CAS  Google Scholar 

  21. F. Moreau, A. Durán, and F. Munoz, J. Eur. Ceram. Soc. 29, 1895 (2009).

    Article  CAS  Google Scholar 

  22. A. Radu, G. Borodi, R. Stefan, et al., Mater. Chem. Phys. 143, 1271 (2014).

    Article  CAS  Google Scholar 

  23. J. Sulowska, I. Maclawska, and Z. Olejniczak, Vibrat. Spectrosc. 65, 44 (2013).

    Article  CAS  Google Scholar 

  24. M. Szumera, Spectrochim. Acta, Part A 129, 601 (2014).

    Article  CAS  Google Scholar 

  25. R. K. Brow, D. R. Tallant, J. J. Hudgens, et al., J. Non-Cryst. Solids 177, 221 (1994).

    Article  CAS  Google Scholar 

  26. S. Agathopoulos, D. U. Tulyaganov, and J. M. G. Ventura, J. Non-Cryst. Solids 352, 322 (2006).

    Article  CAS  Google Scholar 

  27. C. Roiland, F. Fayon, P. Simon, and D. Massiot, J. Non-Cryst. Solids 357, 1636 (2011).

    Article  CAS  Google Scholar 

  28. E. V. Belova, Ya. A. Koluagin, and I. A. Uspenskay, J. Non-Cryst. Solids 423–424, 50 (2015).

    Article  Google Scholar 

  29. M. Tatsumisago, Y. Kowada, and T. Minami, J. Non-Cryst. Solids 150, 207 (1992).

    Article  CAS  Google Scholar 

  30. R. Christensen, J. Byer, G. Olson, and S. W. Martin, J. Non-Cryst. Solids 358, 826 (2012).

    Article  CAS  Google Scholar 

  31. G. D. L. K. Jayasinghe, F. W. S. K. Bandaranayake, and J. L. Souquet, Solid State Ionics 86–88, 447 (1996).

    Article  Google Scholar 

  32. N. Ahlawat, P. Aghamkar, and A. Agarwal, Physica B 414, 103 (2013).

    Article  CAS  Google Scholar 

  33. S. H. Lee, K. I. Cho, J. B. Choi, and D. W. Shin, J. Power Sources 162, 1341 (2006).

    Article  CAS  Google Scholar 

  34. C. Xiaofeng, L. Deming, Z. Shouyuan, T. Lidong, et al., Trans. Mat. Res. Soc. Jpn. 15A, 37 (1994).

    Google Scholar 

  35. S. V. Pillips and P. W. McMillan, Glass Technol. 6 (2), 46 (1965).

    Google Scholar 

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    S. V. Pershina, A. A. Raskovalov, B. D. Antonov, O. G. Reznitskikh, E. G. Vovkotrub & N. N. Batalov

  2. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    N. I. Kadyrova

Authors
  1. S. V. Pershina
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  2. A. A. Raskovalov
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  3. B. D. Antonov
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  4. O. G. Reznitskikh
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  5. E. G. Vovkotrub
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  6. N. N. Batalov
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  7. N. I. Kadyrova
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Correspondence to S. V. Pershina.

Additional information

Original Russian Text © S.V. Pershina, A.A. Raskovalov, B.D. Antonov, O.G. Reznitskikh, E.G. Vovkotrub, N.N. Batalov, N.I. Kadyrova, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 11, pp. 1675–1683.

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Pershina, S.V., Raskovalov, A.A., Antonov, B.D. et al. Structure and properties of (1–x)LiPO3−x SiO2 and 50Li2O−(50–x)P2O5−x SiO2 glass-forming systems. Russ. J. Phys. Chem. 90, 2194–2201 (2016). https://doi.org/10.1134/S0036024416110200

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  • DOI: https://doi.org/10.1134/S0036024416110200

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