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Helium diffusion in aqueous sodium chloride solution at high pressures

  • Physical Chemistry of Solutions
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Abstract

A molecular dynamic investigation of self-diffusion coefficients of helium and water in aqueous NaCl solution is performed. To understand the nonlinear behavior of the self-diffusion coefficients, a number of structural characteristics (radial distribution functions, hydrogen bond network topology) are calculated. The electrolyte concentration range is discussed in which a local increase in helium self-diffusion coefficient is observed. It is shown that this behavior is caused by a breakdown of the network of hydrogen bonds due to competition between ion positions in the states of solvent-separated and contact pairs.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045, Russia

    D. V. Ivlev & M. G. Kiselev

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  1. D. V. Ivlev
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  2. M. G. Kiselev
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Correspondence to M. G. Kiselev.

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Original Russian Text © D.V. Ivlev, M.G. Kiselev, 2012, published in Zhurnal Fizicheskoi Khimii, 2012, Vol. 86, No. 6, pp. 1082–1086.

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Ivlev, D.V., Kiselev, M.G. Helium diffusion in aqueous sodium chloride solution at high pressures. Russ. J. Phys. Chem. 86, 974–978 (2012). https://doi.org/10.1134/S003602441206012X

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  • DOI: https://doi.org/10.1134/S003602441206012X

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