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Crystal structure of thallium(I) 2-thiobarbiturate

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Abstract

The crystal and molecular structures of thallium(I) thiobarbiturate C4H3N2O2STl (C4H4N2O2S is 2-thiobarbituric acid, Н2ТВА) have been determined. Crystallographic data for Tl(НТВА) are a = 11.2414(7) Å, b = 3.8444(3) Å, с = 14.8381(9) Å, β = 99.452(2)°, V = 649.00(7) Å3, space group P2/с, Z = 4. Each of the two independent thallium ions is bonded to four oxygen and two sulfur atoms to form a distorted tetrahedron. N‒H…O and C‒H…S hydrogen bonds form a branched three-dimensional network. The structure is also stabilized by π‒π interaction between heterocyclic НТВА- ions. The IR spectra of Tl(НТВА) agree with X-ray powder diffraction data. The compound is also stable below 280°C, and Tl2SO4 is one of the thermolysis products in an oxidative medium in the region of 500‒650°C.

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References

  1. Biological Inorganic Chemistry, Ed. by I. Bertini, H. B. Gray, E. I. Stiefel, and J. Valentine (BINOM. Laboratoriya Znanii, Moscow, 2013), Vol.1.

  2. K. M. Coup and P. J. Swedlund, Chem. Geol. 398, 97 (2015).

    Article  CAS  Google Scholar 

  3. A. Turner, D. Turner, and C. Braungardt, Marine Pollut. Bull 69, 172 (2013).

    Article  CAS  Google Scholar 

  4. M. A. McGuire, T. K. Reynolds, and F. J. DiSalvo, Chem. Mater. 17, 2875 (2005).

    Article  CAS  Google Scholar 

  5. S. Bondock, T. A. El-Gaber, and A. A. Fadda, Phosphorus Sulfur Silicon Relat. Elem. 182, 1915 (2007).

    Article  CAS  Google Scholar 

  6. R. Ya. Levina and F. K. Velichko, Russ. Chem. Rev. 29, 437 (1960).

    Article  Google Scholar 

  7. V. K. Ahluwalia and R. Aggarwal, Proc. Ind. Nat. Acad. Sci. 5, 369 (1996).

    Google Scholar 

  8. J. H. Lee, S. Lee, M. Y. Park, and H. J. Myung, Virology 8, 18 (2011).

    Article  CAS  Google Scholar 

  9. N. R. Penthala, P. R. Ponugoti, V. Kasam, and P. A. Crooks, Bioorg. Med. Chem. Lett. 23, 1442 (2013).

    Article  CAS  Google Scholar 

  10. M. A. El-Gahami, S. A. Ibrahim, and H. M. A. Salman, Synth. React. Inorg. Met.-Org. Chem. 21, 1497 (1991).

    Article  CAS  Google Scholar 

  11. V. I. Balas, I. I. Verginadis, G. D. Geromichalos, et al., Eur. J. Med. Chem. 46, 2835 (2011).

    Article  CAS  Google Scholar 

  12. N. N. Golovnev and M. S. Molokeev, 2-Thiobarbituric Acid and Its Complexes with Metals: Synthesis, Structure, Properties (Siberian Federal Univ., Krasnoyarsk, 2014) [in Russian].

    Google Scholar 

  13. M. Kubicki, A. Owczarzak, V. I. Balas, et al., J. Coord. Chem. 65, 1107 (2012).

    Article  CAS  Google Scholar 

  14. N. N. Golovnev, M. S. Molokeev, and M. Y. Belash, J. Struct. Chem. 54, 566 (2013).

    Article  CAS  Google Scholar 

  15. Bruker AXS TOPAS V4: General Profile and Structure Analysis Software for Powder Diffraction Data—User’s Manual (Bruker, Karlsruhe, 2008).

  16. Cambridge Structural Database, Ver. 5.34 (Univ. of Cambridge, Cambridge, UK, 2012).

  17. PLATON: A Multipurpose Crystallographic Tool (Utrecht Univ. Utrecht, The Netherlands, 2008).

  18. J. V. Steed and J. L. Atwood, Supramolecular Chemistry (Wiley, Chichester, 2000; Akademkniga, Moscow, 2007).

    Google Scholar 

  19. N. N. Golovnev and M. S. Molokeev, Zh. Strukt. Khim. 55, 122 (2014).

    Google Scholar 

  20. M. R. Chierotti, L. Ferrero, N. Garino, et al., Chem. Eur. J. 16, 4347 (2010).

    Article  CAS  Google Scholar 

  21. N. A. Smorygo and B. A. Ivin, Khim. Geterotsikl. Soedin., No. 10, 1402 (1975).

    Google Scholar 

  22. F. Ramondo, A. Pieretti, L. Gontrani, and L. Bencivenni, Chem. Phys. 271, 293 (2001).

    Article  CAS  Google Scholar 

  23. E. Mendez, M. F. Cerda, J. S. Gancheff, et al., J. Phys. Chem. C 111, 3369 (2007).

    Article  CAS  Google Scholar 

  24. N. N. Golovnev, M. S. Molokeev, S. N. Vereshchagin, et al., Polyhedron 70, 71 (2014).

    Article  CAS  Google Scholar 

  25. V. A. Rabinovich and Z. Ya. Khavin, The Concise Handbook of Chemistry (Khimiya, Leningrad, 1978).

    Google Scholar 

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Authors and Affiliations

  1. Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk, 660041, Russia

    N. N. Golovnev

  2. Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, 660036, Russia

    M. S. Molokeev

  3. Far Eastern State Transport University, ul. Serysheva 47, Khbarovsk, 680021, Russia

    M. S. Molokeev

Authors
  1. N. N. Golovnev
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  2. M. S. Molokeev
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Correspondence to N. N. Golovnev.

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Original Russian Text © N.N. Golovnev, M.S. Molokeev, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 4, pp. 463–467.

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Golovnev, N.N., Molokeev, M.S. Crystal structure of thallium(I) 2-thiobarbiturate. Russ. J. Inorg. Chem. 61, 442–446 (2016). https://doi.org/10.1134/S0036023616040100

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