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Effect of the synthesis conditions on the crystal, local, and electronic structure of Ce 3+1-x Ce 4+ x AlO3 + x/2

  • Physical Methods of Investigation
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Abstract

Cerium monoaluminate Ce 3+1-x Ce 4+ x AlO3+x/2 powders with low contents of Ce4+ cations (х ~ 0.052) were synthesized. A set of modern local structure sensitive methods of analysis, including X-ray absorption spectroscopy and Raman spectroscopy, were used to study the crystal, local, and electronic structures of the synthesized compounds. The degree of reduction and the thermal stability to oxidation of reduced powders depend not only on the reduction conditions but also on the conditions of heat pretreatment of the initial samples. It was concluded that the reaction 4CeAlO3 + O2 ↔ 4CeO2 + 2Al2O3 is reversible.

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Authors and Affiliations

  1. National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Kashirskoe sh. 31, Moscow, 115409, Russia

    V. V. Popov, A. P. Menushenkov, A. S. Sharapov, V. A. Kabanova & A. A. Yastrebtsev

  2. National Research Center Kurchatov Institute, pl. Akademika Kurchatova 1, Moscow, 123182, Russia

    Ya. V. Zubavichus

  3. JSC All-Russian Research Institute of Chemical Technology, Kashirskoe sh. 33, Moscow, 115409, Russia

    L. A. Arzhatkina, N. A. Tsarenko & A. M. Strel’nikova

  4. Peoples’ Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow, 117198, Russia

    V. V. Kurilkin

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  1. V. V. Popov
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  2. A. P. Menushenkov
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  3. Ya. V. Zubavichus
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  4. A. S. Sharapov
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  5. V. A. Kabanova
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  6. A. A. Yastrebtsev
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  7. L. A. Arzhatkina
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  8. N. A. Tsarenko
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  9. A. M. Strel’nikova
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Correspondence to V. V. Popov.

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Original Russian Text © V.V. Popov, A.P. Menushenkov, Ya.V. Zubavichus, A.S. Sharapov, V.A. Kabanova, A.A. Yastrebtsev, L.A. Arzhatkina, N.A. Tsarenko, A.M. Strel’nikova, V.V. Kurilkin, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 2, pp. 238–244.

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Popov, V.V., Menushenkov, A.P., Zubavichus, Y.V. et al. Effect of the synthesis conditions on the crystal, local, and electronic structure of Ce 3+1-x Ce 4+ x AlO3 + x/2 . Russ. J. Inorg. Chem. 61, 225–231 (2016). https://doi.org/10.1134/S0036023616020170

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  • DOI: https://doi.org/10.1134/S0036023616020170

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