Abstract
Protolytic and coordination equilibria in ternary systems containing a nickel(II) salt, ethylenediaminetetraacetic acid, and monoamine complexones, such as iminodiacetic, hydroxyethyliminodiacetic, and nitrilotriacetic acids, were studied by absorption spectroscopy against the background of NaClO4 at I = 0.1 and T = (20 ± 2)°C. Experimental data were processed by mathematical models that were able of evaluating the possibility of existence of a wide spectrum of species in solution and to select the species sufficient for the experimental data to be reproduced from them. The compositions of polynuclear heteroligand complexonates were determined, the pH regions of their existence were established, and the equilibrium constants of reactions and the stability constants of the complexes were calculated.
Similar content being viewed by others
References
V. I. Kornev and N. S. Buldakova, Khim. Fiz. Mezoskop. 14, 285 (2012).
N. S. Buldakova, V. I. Kornev, and T. N. Kropacheva, Vestn. Udmurt. Univ., Fiz. Khim., No. 4, 72 (2012).
V. I. Kornev and N. S. Buldakova, Butlerovskie Soobshch. 31(8), 30 (2012).
A. Ya. Fridman, N. N. Barkhanova, and O. E. Vshivtseva, Zh. Neorg. Khim. 26, 1792 (1981).
Yu. I. Sal’nikov, A. N. Glebov, and F. V. Devyatov, Polynuclear Complexes in Solutions (Kazansk. Gos. Univ., Kazan, 1989) [in Russian].
P. Gans, A. Sabatini, and A. Vacca, Talanta 43, 1739 (1996).
ACD/ChemCketch for Academic and Personal Use.URL: http://www.acdlabs.com/resources/chemsketch/query date: August 25, 2013.
R. N. Patel, N. Singh, R. P. Shrivastava, et al., Proc. Ind. Acad. Sci. (Chem. Sci.) 114(2), 115 (2002).
J. Torres, C. Kremer, E. Kremer, et al., Inorg. Chim. Acta 355, 175 (2003).
N. M. Dyatlova, V. Ya. Temkina, and K. I. Popov, The Complexones and Metal Complexonates (Khimiya, Moscow, 1988) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.I. Kornev, N.S. Buldakova, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 3, pp. 453–457.
Rights and permissions
About this article
Cite this article
Kornev, V.I., Buldakova, N.S. Protolytic and coordination equilibria in aqueous solutions of nickel(II) complexonates. Russ. J. Inorg. Chem. 60, 398–402 (2015). https://doi.org/10.1134/S0036023615030109
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023615030109