Abstract
The crystal and local atomic structures of cobalt nanoparticles in a polymer material have been studied by X-ray absorption spectroscopy and X-ray diffraction. The polymer matrix of the samples was an acrylic acid (AA)—ethyl methacrylate (EMA) copolymer. The cobalt content of the samples was 20.45–50.70 wt %; the AA: EMA ratio in the polymer varied from 1: 10 to 1: 100. The structure of cobalt nanoparticles has been determined. Correlations have been revealed between the oxide-to-metal ratio in nanoparticles and the composition of nanocomposite polymer materials.
Similar content being viewed by others
References
A. D. Pomogailo, Metal Nanoparticles in Polymers (Khimiya, Moscow, 2000) [in Russian].
S. P. Gubin, Yu. A. Koksharov, G. B. Khomutov, et al., Usp. Khim. 74, 539 (2005).
R. Torchio, C. Meneghini, S. Mobilio, et al., J. Magn. Magn. Mater. 322, 3565 (2010).
Jong-Il Park and Jinwoo Cheon, J. Am. Chem. Soc. 123, 5743 (2001).
T.-J. Kühn, W. Caliebe, and N. Matoussevitch, et al., Appl. Organomet. Chem. 25, 577 (2011).
D. J. Sprouster, R. Giulian, L. L. Araujo, et al., J. Appl. Phys. 107, 1 (2010).
Guangjun Cheng, J. D. Carter, and Ting Guo, Chem. Phys. Lett. 400, 122 (2004).
S. A. Voitsikhovskaya, M. E. Sokolov, and V. T. Panyushkin, Zh. Prikl. Khim. 85, 1186 (2012).
S. A. Voytsihovskaya, M. E. Sokolov, V. T. Panyushkin, et al., J. Appl. Spectrosc, 79, 988 (2013).
D. I. Kochubei, Yu. A. Babanov, K. I. Zamaraev, et al., X-ray Absorption Spectral Method of Studying the Structure of Amorphous Objects: EXAFS Spectroscopy (Nauka, Sib. Otd., Novosibirsk, 1988) [in Russian].
M. Newville, J. Synchrotron Rad., No. 8, 96 (2001).
S. I. Zabinski, J. J. Rehr, A. Ankudinov, et al., Phys. Rev. 52, 2995 (1995).
I. Naray-Szabo, Inorganic Crystal Chemistry (Akademiai Kiado, Budapest, 1969).
V. F. Punte, K. M. Krishnan, and P. Alivisatos, Appl. Phys. Lett. 78, 2187 (2001).
M. M. van Schooneveld, R. Kurian, A. Juhin, et al., J. Phys. Chem. 116, 15218.
N. Braidy, S. Behal, A. Adronov, et al., Micron 39, 717 (2008).
D. P. Dinega and M. G. Bawendi, Angew. Chem., Int. Ed. Engl. 38, 1788 (1999).
S. E. Inderhees, J. A. Borchers, K. Green, et al., Phys. Rev. Lett. 101, 117202 (2008).
O. Margeat, C. Amiens, B. Chaudret, et al., Chem. Mater. 17, 107 (2005).
A. F. Gross, M. R. Diehl, K. C. Beverly, et al., J. Phys. Chem. 107, 5475 (2003).
T.-J. Kuhn, W. Caliebe, N. Matoussevitch, et al., Appl. Organomet. Chem. 25, 577 (2011).
U. Wiedwald, M. Spasova, E. L. Salabas, et al., Phys. Rev. 68, 064424 (2003).
S. Rudenkiy, M. Frerichs, F. Voigts, et al., Appl. Organomet. Chem. 18, 553 (2004).
E. V. Makshina, S. V. Sirotin, M. W. E. Berg, et al., Appl. Catal. A: Gen. 312, 59 (2006).
S. Behrens, H. Bönnemann, N. Matoussevitch, et al., Z. Phys. Chem. 220, 3 (2006).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.A. Voitsikhovskaya, M.E. Sokolov, V.T. Panyushkin, V.G. Vlasenko, Ya.V. Zubavichus, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 2, pp. 259–265.
Rights and permissions
About this article
Cite this article
Voitsikhovskaya, S.A., Sokolov, M.E., Panyushkin, V.T. et al. Local atomic structure of cobalt nanoparticles in a polymer matrix. Russ. J. Inorg. Chem. 60, 219–224 (2015). https://doi.org/10.1134/S0036023615020217
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023615020217