Russian Journal of Inorganic Chemistry

, Volume 59, Issue 5, pp 431–440

Electrochemical and chemical synthesis and structure of adducts (CH3OH and H2O) of metal chelates of N,N,O tridentate pyrazole-containing Schiff base

  • D. A. Garnovskii
  • A. S. Antsyshkina
  • A. V. Churakov
  • G. G. Sadikov
  • V. S. Sergienko
  • I. S. Vasil’chenko
  • A. I. Uraev
  • V. G. Vlasenko
  • Ya. V. Zubavichus
  • S. I. Levchenkov
  • Yu. V. Revinskii
  • A. S. Burlov
Coordination Compounds

DOI: 10.1134/S0036023614050088

Cite this article as:
Garnovskii, D.A., Antsyshkina, A.S., Churakov, A.V. et al. Russ. J. Inorg. Chem. (2014) 59: 431. doi:10.1134/S0036023614050088

Abstract

Chemical and electrochemical synthesis of a series of cobalt(II), nickel(II), copper(II), and zinc(II) complexes of tridentate Schiff base (H2L), a product of condensation of N-(2-aminophenyl)-4-methylbenzenesulfonamide (2-tosylaminoaniline) with 1-phenyl-3-methyl-4-formylpyrazol-5-ol was accomplished. The structure and composition of metal-chelates were established by the C, H, N elemental analysis, IR, 1H NMR, EXAFS spectroscopy and magnetochemical data. The structures of all complexes were confirmed by of X-ray crystallography.

Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • D. A. Garnovskii
    • 1
    • 3
  • A. S. Antsyshkina
    • 2
  • A. V. Churakov
    • 2
  • G. G. Sadikov
    • 2
  • V. S. Sergienko
    • 2
  • I. S. Vasil’chenko
    • 3
  • A. I. Uraev
    • 3
  • V. G. Vlasenko
    • 4
  • Ya. V. Zubavichus
    • 5
  • S. I. Levchenkov
    • 1
  • Yu. V. Revinskii
    • 1
  • A. S. Burlov
    • 3
  1. 1.South Research CenterRussian Academy of SciencesRostov-na-DonuRussia
  2. 2.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-na-DonuRussia
  4. 4.Research Institute of PhysicsSouthern Federal UniversityRostov-na-DonuRussia
  5. 5.Russian Research Center “Kurchatov Institute”MoscowRussia

Personalised recommendations