Abstract
The influence of matrix composition, coactivators, and excitation method on the luminescence kinetics of Eu3+ ions in lithium–phosphate and lithium–phosphate–borate glasses activated by Eu, Eu/Tb, and Eu/Dy is studied. Luminescence is excited by a high current electron beam and a xenon lamp. It is found that, under photoexcitation, the europium luminescence decays more slowly than under electronic excitation. Depending on the content of cation modifiers ZnO and Li2O, the decay time decreases with increasing amount of ZnO. The decay time weakly depends on the europium concentration. The decay of the luminescence of europium ions is well described by the Inokuti–Hirayama model.
Similar content being viewed by others
References
Handbook on the Physics and Chemistry of Rare Earths, Ed. by C. Görler-Walrand, K. Binnimans, Jr. Gschneidner, and L. Eyring (North-Holland, Amsterdam, 1998), Vol. 25, Chap.167.
S. Surendra Babu, P. Babu, et al., J. Lumin. 126, 109 (2007).
S. Z. Shmurak, A. P. Kiselev, D. M. Kurmasheva, B. S. Red’kin, and V. V. Sinitsyn, J. Exp. Theor. Phys. 110, 759 (2010).
R. Reisfeld, E. Zigansky, and M. Gaft, Mol. Phys. 102, 1319 (2004).
R. T. Wegh, H. Donker, K. D. Oskam, and A. Meijerink, Science 283 (5402), 663 (1999).
S. N. Bagaev, V. I. Dashkevich, V. A. Orlovich, S. M. Vatnik, A. A. Pavlyuk, and A. M. Yurkin, Quantum Electron. 41, 189 (2011).
Xiaolan Gao, Wang Yuhua, and Liu Bitao, J. Lumin. 129, 840 (2009).
E. F. Polisadova, H. A. Othman, and V. M. Lisitsyn, Funct. Mater. 20, 290 (2013).
E. F. Polisadova, H. A. Othman, and V. M. Lisitsyn, Glass Phys. Chem. 40, 138 (2014).
E. F. Polisadova, D. T. Valiev, K. N. Belikov, and N. L. Egorova, Glass Phys. Chem. 41, 98 (2015).
Cathodoluminescence, Ed. by Naoki Yamamoto (InTech, Croatia, 2012), Chap. 3, p. 324.
M. Inokuti and F. J. Hirayama, Chem. Phys. 43, 1978 (1965).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.F. Polisadova, H.A. Othman, D.T. Valiev, 2016, published in Optika i Spektroskopiya, 2016, Vol. 121, No. 4, pp. 536–540.
Rights and permissions
About this article
Cite this article
Polisadova, E.F., Othman, H.A. & Valiev, D.T. Luminescence decay kinetics of Eu3+ ions in phosphate glasses of different composition under photo- and electron excitations. Opt. Spectrosc. 121, 487–491 (2016). https://doi.org/10.1134/S0030400X16100192
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0030400X16100192