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Synthesis, characterization, and application of cobalt hydrogen sulfate as a new heterogeneous, reusable and efficient catalyst in one-pot synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes and 1,8-dioxooctahydroxanthenes

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Abstract

Cobalt hydrogen sulfate is synthesized and characterized by XRD, FTIR and TEM measurements. The efficiency of this readily available, cheap, non-toxic, heterogeneous and reusable catalyst is shown in the one-pot preparation of aryl- and alkyl-14H-dibenzoxanthenes and 1,8-dioxooctahydroxanthene derivatives by cyclocondensation of substituted benzaldehydes and β-naphthol or 5,5-dimethyl-1,3-cyclohexanedione respectively. Among advantages of these methods are high yields, a clean reaction strategy, simple methodology, green conditions and easy workup.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, 91775-1436, Iran

    H. Eshghi, M. Rahimizadeh, M. Eftekhar & M. Bakavoli

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  1. H. Eshghi
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  2. M. Rahimizadeh
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  3. M. Eftekhar
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  4. M. Bakavoli
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Correspondence to H. Eshghi.

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Eshghi, H., Rahimizadeh, M., Eftekhar, M. et al. Synthesis, characterization, and application of cobalt hydrogen sulfate as a new heterogeneous, reusable and efficient catalyst in one-pot synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes and 1,8-dioxooctahydroxanthenes. Kinet Catal 55, 428–433 (2014). https://doi.org/10.1134/S0023158414040041

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  • DOI: https://doi.org/10.1134/S0023158414040041

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