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Coherence-assembly in structures with clusters of heavy cations

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Abstract

Crystallographic analysis is used to investigate the mutual packing arrangements of cluster groupings in the structures of KNa23O4(H2O)48[{Rh4O2(H2O)2}(H2W9O33)2] (I), (NH4)2[H3Mo57V6(NO)6O183(H2O)18]· ·53H2O (II), and Na6Sr2[W12O40(OH)2]·24H2O (III). It is found that all heavy cations in the clusters are located near the nodes of the single sublattice of the crystal. This arrangement ensures the coherence-assembly of the structural fragments since both the mutual orientation of the fragments and intervals between them are defined by the single cation sublattice.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. V. Borisov, S. A. Magarill & N. V. Pervukhina

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  1. S. V. Borisov
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  2. S. A. Magarill
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  3. N. V. Pervukhina
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Correspondence to S. V. Borisov.

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Original Russian Text © 2015 S. V. Borisov, S. A. Magarill, N. V. Pervukhina.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 56, No. 2, pp. 297–303, March–April, 2015.

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Borisov, S.V., Magarill, S.A. & Pervukhina, N.V. Coherence-assembly in structures with clusters of heavy cations. J Struct Chem 56, 281–288 (2015). https://doi.org/10.1134/S0022476615020110

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  • DOI: https://doi.org/10.1134/S0022476615020110

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